WebMO Job Summary
199226: C8H14O (R,R)-2,6-dimethylcyclohexanone, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ
Method
B3LYP
Stoichiometry
C
8
H
14
O
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-388.637741222 Hartree
ZPE
0.206236 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-388.422097 Hartree
Enthalpy
-388.421152 Hartree
Free Energy
-388.465395 Hartree
C
v
36.100 cal/mol-K
Entropy
93.116 cal/mol-K
Dipole Moment
3.1442 Debye
Server
class (200289)
CPU time
6430.6 sec
Geometry Sequence Energies
Step
Energy (au)
0
-388.632652320
1
-388.637420384
2
-388.637255818
3
-388.637631715
4
-388.637711161
5
-388.637737837
6
-388.637741064
7
-388.637741222
8
-388.637741222
9
-388.637741222
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.06914
0.06901908119
b
1.56336
0.05214807639
c
1.10037
0.03670439234
Partial Charges
Atom
Symbol
Charge
1
C
-0.249218
2
C
-0.259873
3
C
-0.239926
4
C
0.293801
5
C
0.232742
6
C
0.081240
7
H
0.099562
8
C
-0.461803
9
H
0.124938
10
H
0.119766
11
H
0.140057
12
O
-0.448991
13
H
0.088303
14
C
-0.557914
15
H
0.136300
16
H
0.139501
17
H
0.113689
18
H
0.109621
19
H
0.107076
20
H
0.105973
21
H
0.110377
22
H
0.112561
23
H
0.102216
Vibrational Modes
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Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
72.7714
2.9225
2
A
124.3572
0.1653
3
A
193.6982
0.3734
4
A
210.5089
0.0302
5
A
219.0548
0.5451
6
A
262.3155
0.6512
7
A
293.6450
2.4326
8
A
337.5365
0.2527
9
A
367.4716
0.2553
10
A
398.4860
5.8644
11
A
469.5810
1.3973
12
A
533.2013
3.2208
13
A
627.7113
1.0252
14
A
669.1429
0.2634
15
A
741.9169
2.8652
16
A
828.0776
0.6905
17
A
848.6286
1.0449
18
A
867.3677
11.7413
19
A
903.1367
1.7441
20
A
953.6984
7.7943
21
A
971.4734
12.3824
22
A
989.6318
4.5146
23
A
1007.2127
7.6946
24
A
1046.9786
5.2905
25
A
1087.1069
0.9029
26
A
1095.7171
3.6267
27
A
1131.5626
0.3131
28
A
1143.5509
13.4163
29
A
1164.5977
1.7931
30
A
1210.6748
5.7855
31
A
1242.9783
10.0587
32
A
1280.8671
3.4646
33
A
1312.0772
0.5778
34
A
1338.4355
0.6991
35
A
1346.0790
4.5161
36
A
1348.9218
1.2134
37
A
1373.1990
2.6328
38
A
1384.9819
4.1281
39
A
1390.1213
1.3489
40
A
1410.6031
5.0345
41
A
1417.3891
6.6181
42
A
1487.5919
4.1481
43
A
1489.3345
1.3415
44
A
1494.2643
8.7428
45
A
1498.2516
4.4477
46
A
1499.9748
11.3160
47
A
1506.3804
5.7060
48
A
1508.7056
7.9269
49
A
1763.0335
200.6445
50
A
2980.6722
7.1945
51
A
3004.7151
27.0417
52
A
3009.0731
24.0310
53
A
3015.7371
15.2938
54
A
3028.9187
23.2036
55
A
3033.2639
29.2965
56
A
3044.8664
41.4316
57
A
3049.4605
51.5421
58
A
3052.2397
1.7052
59
A
3057.1607
58.7224
60
A
3088.2623
23.1796
61
A
3092.0406
22.8068
62
A
3098.1220
35.7603
63
A
3108.6951
18.9451
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
Cherishing children is the mark of a civilized society. -- Joan Ganz Cooney