WebMO Job Summary

199469: C5H11Cl, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ
Method B3LYP
Stoichiometry C5H11Cl
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -657.37150087 Hartree
ZPE 0.151956 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -657.211679 Hartree
Enthalpy -657.210734 Hartree
Free Energy -657.251093 Hartree
Cv 28.737 cal/mol-K
Entropy 84.942 cal/mol-K
Dipole Moment 2.3973 Debye
Server class (200532)
CPU time 539.2 sec

Geometry Sequence Energies

Step Energy (au)  
0 -657.367678511  
1 -657.371190509  
2 -657.371436578  
3 -657.371487686  
4 -657.371499528  
5 -657.371500709  
6 -657.371500870  
7 -657.371500870  
8 -657.371500870  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.98851 0.09968596341
b 2.34927 0.07836321219
c 1.88830 0.06298690810

Partial Charges

Atom Symbol Charge
1 C -0.428552  
2 C -0.036489  
3 C -0.237519  
4 C -0.453360  
5 H 0.146651  
6 H 0.145707  
7 H 0.172487  
8 H 0.153083  
9 H 0.139703  
10 C -0.432643  
11 H 0.170125  
12 H 0.148598  
13 H 0.163557  
14 Cl -0.128015  
15 H 0.148620  
16 H 0.163861  
17 H 0.164187  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A 105.08 (109.4626) 0.3008
2 A 200.78 (209.1464) 0.8943
3 A 230.13 (239.7198) 0.1267
4 A 250.76 (261.2109) 0.1043
5 A 281.12 (292.8301) 0.0557
6 A 288.09 (300.0984) 0.8874
7 A 315.75 (328.9088) 0.8603
8 A 352.87 (367.5765) 5.4129
9 A 382.31 (398.2398) 0.6238
10 A 470.25 (489.8456) 0.6301
11 A 524.74 (546.6052) 32.0965
12 A 745.32 (776.3752) 5.8526
13 A 772.75 (804.9493) 16.3280
14 A 893.64 (930.8709) 4.5500
15 A 915.02 (953.1477) 0.2250
16 A 983.10 (1024.0664) 0.9390
17 A 983.83 (1024.8263) 4.2071
18 A 1044.76 (1088.2870) 2.0203
19 A 1047.56 (1091.2038) 3.8318
20 A 1136.98 (1184.3549) 42.1177
21 A 1178.34 (1227.4425) 10.2539
22 A 1214.99 (1265.6104) 7.8761
23 A 1280.97 (1334.3453) 6.0868
24 A 1340.35 (1396.1936) 0.4562
25 A 1373.93 (1431.1774) 7.5999
26 A 1384.73 (1442.4234) 5.1412
27 A 1391.56 (1449.5382) 5.1445
28 A 1439.95 (1499.9476) 0.0799
29 A 1451.51 (1511.9944) 0.3950
30 A 1455.93 (1516.5909) 3.5339
31 A 1463.29 (1524.2572) 3.2991
32 A 1469.37 (1530.5940) 9.1157
33 A 1475.65 (1537.1396) 8.4314
34 A 1481.33 (1543.0541) 0.8720
35 A 2904.53 (3025.5513) 19.3014
36 A 2925.55 (3047.4486) 9.9253
37 A 2931.90 (3054.0591) 33.9140
38 A 2937.10 (3059.4760) 20.4429
39 A 2957.36 (3080.5786) 10.6705
40 A 2994.50 (3119.2729) 6.2053
41 A 2996.23 (3121.0679) 35.6597
42 A 3000.24 (3125.2530) 27.7062
43 A 3012.39 (3137.9074) 22.6925
44 A 3018.90 (3144.6831) 21.0960
45 A 3027.66 (3153.8134) 17.6981
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

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