WebMO Job Summary
199576: C6H10 2,3-dimethyl-1,3-butadiene C2 perpendicular, Transition State Optimization - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT=(TS,NoEigenTest,NewEstmFC) freq
Method
B3LYP
Stoichiometry
C
6
H
10
Symmetry
C2
Basis
6-311+G(2d,p)
RB3LYP Energy
-234.69424218 Hartree
ZPE
0.140148 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-234.547451 Hartree
Enthalpy
-234.546507 Hartree
Free Energy
-234.583189 Hartree
C
v
24.908 cal/mol-K
Entropy
77.205 cal/mol-K
Dipole Moment
0.5108 Debye
Server
class (200630)
CPU time
990.8 sec
Geometry Sequence Energies
Step
Energy (au)
0
-234.694267459
1
-234.694263773
2
-234.694234855
3
-234.694240916
4
-234.694242127
5
-234.694242180
6
-234.694242180
7
-234.694242180
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
4.74649
0.15832586422
b
2.71559
0.09058233213
c
2.41178
0.08044832135
Partial Charges
Atom
Symbol
Charge
1
C
-0.325265
2
C
0.298785
3
C
0.298785
4
C
-0.325265
5
H
0.091177
6
H
0.085689
7
H
0.085689
8
H
0.091177
9
C
-0.511473
10
H
0.128879
11
H
0.121585
12
H
0.110622
13
C
-0.511473
14
H
0.121585
15
H
0.110622
16
H
0.128879
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
-64.8771
0.1446
2
A
193.7623
0.0014
3
B
204.3075
0.1560
4
B
233.5894
1.0100
5
A
246.2069
1.8833
6
A
338.0464
0.0393
7
B
457.5398
1.1056
8
A
561.8392
7.2314
9
B
569.0006
7.2239
10
A
713.1689
0.0096
11
B
735.4958
2.4883
12
A
739.6854
0.5168
13
B
922.2794
8.6609
14
B
927.6064
21.7157
15
A
928.2275
49.5431
16
A
968.8885
0.1006
17
B
1021.7843
5.4986
18
A
1030.2483
0.6209
19
A
1075.1969
0.2962
20
B
1077.1142
0.2250
21
B
1208.6651
8.9769
22
A
1323.1120
1.7480
23
A
1408.9318
1.0883
24
B
1409.0459
6.8050
25
B
1434.1756
0.4602
26
A
1451.9774
0.0001
27
B
1475.7160
5.7724
28
A
1478.8840
12.0734
29
B
1492.6111
18.4973
30
A
1492.6728
4.9249
31
B
1677.7593
33.9786
32
A
1708.3757
12.9768
33
B
3014.8262
22.6706
34
A
3015.8782
22.0325
35
B
3059.7168
11.1228
36
A
3060.5853
17.8638
37
A
3096.7975
0.0158
38
B
3097.2807
49.5967
39
B
3126.6928
14.7179
40
A
3127.1629
2.1299
41
A
3206.2779
2.2912
42
B
3206.5563
26.4007
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
IT IS BY LOGIC THAT WE PROVE, BUT BY INTUITION THAT WE DISCOVER. -- J.H.POINCARE (1854-1912)