WebMO Job Summary

199663: C7H10N2 4-dimethylaminopyridine Cs, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ
Method B3LYP
Stoichiometry C7H10N2
Symmetry CS
Basis 6-311+G(2d,p)
RB3LYP Energy -382.369377032 Hartree
ZPE 0.161090 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -382.199648 Hartree
Enthalpy -382.198704 Hartree
Free Energy -382.241917 Hartree
Cv 31.787 cal/mol-K
Entropy 90.950 cal/mol-K
Dipole Moment 4.7331 Debye
Server class (200713)
CPU time 1703.1 sec

Geometry Sequence Energies

Step Energy (au)  
0 -382.369377032  
1 -382.369377032  
2 -382.369377032  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.62310 0.12085360733
b 1.22278 0.04078755043
c 0.92606 0.03089003660

Partial Charges

Atom Symbol Charge
1 C -0.302141  
2 N -0.067203  
3 C 0.352478  
4 C -0.100687  
5 C -0.118469  
6 N -0.337310  
7 C -0.118469  
8 C -0.100687  
9 H 0.080261  
10 H 0.087027  
11 H 0.087027  
12 H 0.080261  
13 C -0.302141  
14 H 0.119302  
15 H 0.133147  
16 H 0.127577  
17 H 0.127577  
18 H 0.133147  
19 H 0.119302  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A" 82.6099 0.0109
2 A' 90.6136 5.1153
3 A' 141.3013 0.0728
4 A" 168.0714 0.1684
5 A' 265.8840 8.0890
6 A" 266.9189 0.0554
7 A' 393.3811 0.3675
8 A" 405.4008 0.0142
9 A" 479.8050 2.7057
10 A' 538.9535 16.4553
11 A' 553.2124 4.2445
12 A" 683.1926 0.2261
13 A' 750.3232 0.7650
14 A' 761.5815 8.9184
15 A' 813.9277 51.1095
16 A" 827.0443 0.0029
17 A' 962.8442 9.0154
18 A' 965.2973 8.8542
19 A" 995.2046 0.0003
20 A' 1005.9468 50.3492
21 A" 1078.7268 21.5465
22 A' 1091.6629 0.0258
23 A" 1129.9864 3.4018
24 A" 1134.7160 0.4995
25 A' 1145.5252 20.9816
26 A' 1199.8944 5.7641
27 A" 1246.2986 35.3172
28 A' 1256.2028 30.4263
29 A" 1309.9364 0.3745
30 A" 1380.5808 7.2361
31 A' 1387.1304 125.3208
32 A" 1448.0513 0.8825
33 A" 1462.2006 1.2994
34 A" 1486.5245 2.5734
35 A' 1486.6371 17.5826
36 A' 1493.8206 19.2719
37 A" 1512.2157 3.7540
38 A' 1527.6793 13.6645
39 A' 1544.8160 116.5539
40 A" 1579.9115 44.2326
41 A' 1634.8861 306.1355
42 A" 2979.6673 68.7927
43 A' 2985.8744 74.0896
44 A" 3057.0758 14.3065
45 A' 3057.9395 42.5891
46 A" 3116.9279 2.4954
47 A' 3128.3509 32.5555
48 A" 3137.3849 37.6433
49 A' 3140.3503 10.7309
50 A' 3208.8659 3.4887
51 A" 3209.0197 14.3784
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IF YOU GET CONFUSED, LOGIC OUT YOUR DILEMMA -- PICKER X-RAY CORP. DIGITAL PRINTER MANUAL CA. 1964