WebMO Job Summary

200391: Methyl Salicylate, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C8H8O3
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -535.310503297 Hartree
ZPE 0.147646 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -535.153713 Hartree
Enthalpy -535.152768 Hartree
Free Energy -535.198406 Hartree
Cv 35.076 cal/mol-K
Entropy 96.053 cal/mol-K
Dipole Moment 5.7138 Debye
Server batch (202780)
CPU time 1103.4 sec

Geometry Sequence Energies

Step Energy  
0 -534.867267101  
1 -535.258968814  
2 -535.300073118  
3 -535.310033410  
4 -535.310430932  
5 -535.310476066  
6 -535.310488201  
7 -535.310496468  
8 -535.310502080  
9 -535.310503230  
10 -535.310503297  
11 -535.310503297  
12 -535.310503297  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.89000 0.06304361399
b 0.92776 0.03094674250
c 0.62476 0.02083975041

Partial Charges

Atom Symbol Charge
1 C -0.196871  
2 O -0.459311  
3 C 0.580272  
4 C 0.014122  
5 C 0.298125  
6 C -0.194896  
7 C -0.124981  
8 C -0.130008  
9 C -0.173043  
10 H 0.184283  
11 H 0.137861  
12 H 0.140810  
13 H 0.121181  
14 O -0.648413  
15 H 0.414178  
16 O -0.451396  
17 H 0.162375  
18 H 0.163338  
19 H 0.162375  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" -90.4196 4.9273
2 A" 16.5823 0.1352
3 A" 120.6273 0.0016
4 A' 203.8078 0.9412
5 A" 245.8006 1.9151
6 A' 272.2423 6.0422
7 A" 281.4476 0.0406
8 A" 376.8232 104.8889
9 A' 378.8483 2.3485
10 A" 444.6705 0.5025
11 A' 449.1129 1.9598
12 A" 539.2502 6.7393
13 A' 543.1079 4.8748
14 A' 580.5421 7.6339
15 A' 633.7197 26.7121
16 A" 686.1763 12.5364
17 A' 689.5131 1.4265
18 A" 754.8682 46.5280
19 A" 778.1615 16.9487
20 A" 851.1026 0.4110
21 A' 855.3636 14.3348
22 A" 966.1700 0.4985
23 A" 1001.3771 0.5242
24 A' 1008.0413 85.2838
25 A' 1089.2909 5.0840
26 A' 1119.1783 56.3111
27 A' 1163.6674 75.0791
28 A" 1176.7798 0.5299
29 A' 1197.3995 19.6691
30 A' 1208.5113 28.8712
31 A' 1220.6051 28.5540
32 A' 1259.5486 191.0263
33 A' 1302.0981 177.0340
34 A' 1351.9147 208.4545
35 A' 1383.4759 76.2296
36 A' 1488.9501 129.9671
37 A' 1510.0199 1.5970
38 A' 1521.9788 57.1754
39 A" 1529.3251 4.4875
40 A' 1544.0390 10.3409
41 A' 1642.6255 7.3778
42 A' 1660.7798 60.3859
43 A' 1770.0279 274.9339
44 A' 3082.9233 44.9118
45 A' 3158.4805 16.1677
46 A' 3160.5893 29.2401
47 A" 3177.7141 26.0649
48 A' 3198.5762 9.7415
49 A' 3215.4358 16.0686
50 A' 3253.8760 4.6897
51 A' 3743.9711 46.9058
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

MY GROUP MEETINGS AREN'T VERY STRUCTURED. -- PROF. M. S. GORDON, OCT. 5, 1984