WebMO Job Summary

200946: Ethanol, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C2H6O
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -155.033805303 Hartree
ZPE 0.080317 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -154.949215 Hartree
Enthalpy -154.948271 Hartree
Free Energy -154.978863 Hartree
Cv 13.388 cal/mol-K
Entropy 64.387 cal/mol-K
Dipole Moment 1.5624 Debye
Server batch (203335)
CPU time 40.2 sec

Geometry Sequence Energies

Step Energy  
0 -155.024927509  
1 -155.033175345  
2 -155.033740118  
3 -155.033803965  
4 -155.033805303  
5 -155.033805303  
6 -155.033805303  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 34.94941 1.16578683244
b 9.35652 0.31209991280
c 8.13437 0.27133337691

Partial Charges

Atom Symbol Charge
1 C -0.441617  
2 C -0.025930  
3 O -0.613154  
4 H 0.389402  
5 H 0.117969  
6 H 0.117969  
7 H 0.139681  
8 H 0.157840  
9 H 0.157840  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 249.6235 36.2764
2 A" 298.8279 94.9645
3 A' 418.1175 11.2968
4 A" 830.5989 0.0172
5 A' 912.1104 10.0937
6 A' 1043.0197 56.0972
7 A' 1124.2754 23.1243
8 A" 1194.8661 4.8738
9 A' 1292.0537 86.5932
10 A" 1310.7541 0.0798
11 A' 1428.5151 0.4072
12 A' 1482.9966 16.3311
13 A" 1514.1155 4.4104
14 A' 1531.5488 3.0253
15 A' 1561.2585 2.6832
16 A' 2983.0168 73.4154
17 A" 3006.2708 77.6558
18 A' 3058.2238 15.6902
19 A' 3129.0484 31.5557
20 A" 3133.6193 34.4239
21 A' 3752.3844 9.6785
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

Statistics are no substitute for judgment. -- Henry Clay