WebMO Job Summary

200966: C6H6OBr(+1) ortho bromination of phenol arenium, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C6H6BrO(1+)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -2878.88318039 Hartree
ZPE 0.107128 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -2878.768930 Hartree
Enthalpy -2878.767986 Hartree
Free Energy -2878.809010 Hartree
Cv 26.398 cal/mol-K
Entropy 86.343 cal/mol-K
Dipole Moment 6.2107 Debye
Server batch (203355)
CPU time 1694.7 sec

Geometry Sequence Energies

Step Energy  
0 -2878.74274868  
1 -2878.83235232  
2 -2878.87145716  
3 -2878.88003580  
4 -2878.88227108  
5 -2878.88290418  
6 -2878.88311323  
7 -2878.88315944  
8 -2878.88317622  
9 -2878.88317894  
10 -2878.88318006  
11 -2878.88318039  
12 -2878.88318039  
13 -2878.88318039  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.26571 0.07557595061
b 1.13360 0.03781282583
c 0.84932 0.02833026573

Partial Charges

Atom Symbol Charge
1 C -0.300163  
2 C 0.447918  
3 C -0.160447  
4 C -0.083597  
5 C -0.094308  
6 C -0.051692  
7 H 0.241084  
8 H 0.223197  
9 H 0.237921  
10 H 0.213938  
11 O -0.509437  
12 H 0.469565  
13 H 0.284177  
14 Br 0.081842  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 72.5727 5.4004
2 A 160.4766 0.6578
3 A 177.7207 3.5782
4 A 316.2085 1.5798
5 A 420.7945 8.6198
6 A 450.2326 2.2104
7 A 515.2577 6.1313
8 A 534.8763 20.4699
9 A 600.6200 8.2388
10 A 619.6630 80.5270
11 A 737.8480 7.2347
12 A 787.7500 86.3981
13 A 807.8712 7.2507
14 A 878.5235 11.3611
15 A 950.1844 10.3735
16 A 1006.8224 1.4744
17 A 1022.2527 1.0304
18 A 1047.7664 1.6066
19 A 1051.7111 2.4434
20 A 1097.0760 11.4302
21 A 1181.2602 144.2838
22 A 1211.5716 4.9525
23 A 1216.6537 11.8531
24 A 1341.4760 6.3763
25 A 1389.3821 85.2479
26 A 1460.8780 149.6724
27 A 1466.3591 34.5627
28 A 1534.3692 302.3305
29 A 1582.9946 57.0700
30 A 1674.2877 159.4447
31 A 3131.7296 18.2798
32 A 3210.1792 1.3854
33 A 3221.0240 1.7685
34 A 3233.4461 4.9336
35 A 3246.3778 4.3159
36 A 3665.7436 216.9405
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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