WebMO Job Summary

200968: Chiral 1A H Bond, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C5H10O3
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -422.233304253 Hartree
ZPE 0.152361 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -422.071804 Hartree
Enthalpy -422.070860 Hartree
Free Energy -422.114535 Hartree
Cv 33.434 cal/mol-K
Entropy 91.923 cal/mol-K
Dipole Moment 3.8887 Debye
Server batch (203357)
CPU time 1202.1 sec

Geometry Sequence Energies

Step Energy  
0 -422.201046138  
1 -422.211281017  
2 -422.212008628  
3 -422.216866935  
4 -422.220631273  
5 -422.224958721  
6 -422.229004186  
7 -422.232359097  
8 -422.232882883  
9 -422.233066257  
10 -422.233235327  
11 -422.233294948  
12 -422.233302827  
13 -422.233304253  
14 -422.233304253  
15 -422.233304253  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.29404 0.07652093769
b 1.83111 0.06107925504
c 1.59961 0.05335724623

Partial Charges

Atom Symbol Charge
1 C 0.202332  
2 C -0.445420  
3 H 0.162041  
4 H 0.160558  
5 H 0.174708  
6 C -0.277842  
7 C -0.482246  
8 H 0.166180  
9 H 0.128427  
10 H 0.180518  
11 H 0.177342  
12 H 0.146278  
13 C 0.591330  
14 O -0.580653  
15 H 0.424972  
16 O -0.467956  
17 O -0.668001  
18 H 0.407432  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 62.8878 4.2619
2 A 97.8280 1.6248
3 A 189.4176 4.9944
4 A 237.4633 0.5744
5 A 251.9017 2.7860
6 A 259.7691 1.3036
7 A 301.7391 6.9473
8 A 359.8597 101.9350
9 A 368.8627 3.8476
10 A 390.1548 1.1882
11 A 482.5607 6.0022
12 A 538.0845 1.9370
13 A 571.6059 2.9270
14 A 741.5594 15.5397
15 A 753.7684 8.6673
16 A 788.9555 5.6804
17 A 817.6407 67.9826
18 A 889.3020 6.4282
19 A 940.0418 18.0028
20 A 1020.0010 14.7055
21 A 1037.2405 41.0606
22 A 1070.9455 2.7140
23 A 1113.5425 26.3827
24 A 1182.4108 22.7595
25 A 1219.5288 31.9689
26 A 1249.0055 9.8814
27 A 1321.5370 48.8040
28 A 1350.4701 33.5685
29 A 1397.2781 21.6001
30 A 1422.8314 281.6700
31 A 1433.8908 105.1771
32 A 1448.9738 24.9504
33 A 1500.3155 3.0428
34 A 1517.0931 10.8745
35 A 1525.2613 3.7424
36 A 1527.9587 7.0347
37 A 1543.4921 13.2086
38 A 1868.2838 206.1513
39 A 3030.7061 30.0868
40 A 3057.9892 13.9895
41 A 3065.8539 18.7786
42 A 3099.6800 15.0822
43 A 3123.1144 14.7443
44 A 3135.5328 2.0414
45 A 3136.5304 36.1590
46 A 3154.3902 11.9412
47 A 3546.2249 127.7106
48 A 3735.2051 26.3251
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

VIRTUE IS LEARNED AT YOUR MOTHER'S KNEE, VICES ARE PICKED UP AT SOME OTHER JOINT.