WebMO Job Summary

225172: C3H7ON dimethyl formamide Cs, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ
Method B3LYP
Stoichiometry C3H7NO
Symmetry CS
Basis 6-311+G(2d,p)
RB3LYP Energy -248.595277764 Hartree
ZPE 0.101833 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -248.487311 Hartree
Enthalpy -248.486367 Hartree
Free Energy -248.522624 Hartree
Cv 20.029 cal/mol-K
Entropy 76.310 cal/mol-K
Dipole Moment 4.1846 Debye
Server class (226176)
CPU time 345 sec

Geometry Sequence Energies

Step Energy (au)  
0 -248.595278510  
1 -248.595277764  
2 -248.595277764  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 8.91655 0.29742409330
b 4.19196 0.13982873445
c 2.95751 0.09865191472

Partial Charges

Atom Symbol Charge
1 C -0.306738  
2 N 0.027895  
3 C 0.243886  
4 O -0.493854  
5 H 0.066489  
6 C -0.294629  
7 H 0.122979  
8 H 0.122979  
9 H 0.113845  
10 H 0.114700  
11 H 0.167748  
12 H 0.114700  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A" 112.9477 0.2261
2 A" 167.7652 0.0923
3 A" 230.8490 1.1868
4 A' 320.2139 11.4266
5 A" 336.6160 16.9939
6 A' 394.5127 1.7104
7 A' 658.2924 7.0788
8 A' 868.4521 1.7697
9 A" 1016.0066 0.1124
10 A' 1080.4513 7.1272
11 A' 1095.4464 117.9732
12 A" 1129.6686 0.0764
13 A" 1176.9477 2.6610
14 A' 1273.4171 32.9286
15 A' 1410.4880 85.9999
16 A' 1429.5223 15.6016
17 A' 1440.6659 5.8455
18 A' 1469.1529 8.1250
19 A" 1479.6251 3.9624
20 A" 1500.5589 17.4969
21 A' 1504.1500 11.5635
22 A' 1540.1144 23.5797
23 A' 1745.3122 500.8645
24 A' 2942.8529 81.9371
25 A' 3005.3838 47.6095
26 A' 3013.4284 60.2303
27 A" 3047.9846 46.5920
28 A" 3057.1411 17.3756
29 A' 3108.3279 14.8836
30 A' 3143.1192 0.9796
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

A SCIENTIST IS SOMEONE WHOSE CURIOSITY SURVIVES EDUCATION'S ASSAULTS ON IT. - SIR HERMANN BONDI