WebMO Job Summary
225179: C9H10O2Cl(-1) benzylchloride acetate SN2 TS, Transition State Optimization - Gaussian
Raw Output
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT=(TS,NoEigenTest,NewEstmFC) SCRF=(PCM,Solvent=Acetonitrile) FREQ
Method
B3LYP
Stoichiometry
C
9
H
10
ClO
2
(1-)
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-959.968246225 Hartree
ZPE
0.167361 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-959.788073 Hartree
Enthalpy
-959.787129 Hartree
Free Energy
-959.844075 Hartree
C
v
43.633 cal/mol-K
Entropy
119.854 cal/mol-K
Dipole Moment
10.7959 Debye
Server
class (226183)
CPU time
5921 sec
Geometry Sequence Energies
Step
Energy (au)
0
-959.968246225
1
-959.968246225
2
-959.968246225
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
0.83619
0.02789229608
b
0.50987
0.01700743252
c
0.37136
0.01238723624
Partial Charges
Atom
Symbol
Charge
1
C
-0.658126
2
O
-0.565927
3
C
0.702497
4
O
-0.678526
5
C
-0.551235
6
H
0.122802
7
H
0.127218
8
H
0.133598
9
C
2.001598
10
C
-0.745251
11
C
-0.209795
12
C
-0.098972
13
C
-0.162403
14
C
-0.611056
15
H
0.107451
16
H
0.108780
17
H
0.109556
18
H
0.108907
19
H
0.110624
20
H
0.167871
21
H
0.212093
22
Cl
-0.731703
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
-337.5991
1360.3474
2
A
28.0186
3.0671
3
A
30.9010
6.2451
4
A
42.4349
1.1333
5
A
55.7618
1.1211
6
A
77.1737
2.9770
7
A
81.2791
2.6908
8
A
126.6800
72.8068
9
A
155.3429
6.6499
10
A
173.0905
16.7443
11
A
263.9344
59.3890
12
A
385.2381
9.2195
13
A
415.6766
0.0142
14
A
458.4686
8.9754
15
A
516.9051
85.5833
16
A
536.2522
73.6834
17
A
619.3461
25.6200
18
A
635.1472
1.0354
19
A
644.2877
44.9377
20
A
703.4241
67.8973
21
A
781.4532
26.0112
22
A
830.2618
33.8117
23
A
853.9939
0.0003
24
A
903.4331
3.8092
25
A
914.6140
13.2001
26
A
942.8656
2.3567
27
A
989.8742
0.4840
28
A
993.9376
4.1853
29
A
1011.2566
0.4053
30
A
1016.3993
31.1900
31
A
1018.4774
1.1731
32
A
1045.4412
5.7853
33
A
1050.8304
126.9114
34
A
1054.5610
8.4236
35
A
1112.5457
6.8414
36
A
1179.7798
0.5336
37
A
1197.4812
8.6618
38
A
1258.0489
150.4302
39
A
1330.7720
3.3373
40
A
1351.2786
306.3865
41
A
1363.7872
1.1844
42
A
1376.4089
273.4436
43
A
1457.3418
77.3578
44
A
1472.0734
14.7869
45
A
1484.6575
29.7392
46
A
1488.1962
10.4463
47
A
1530.0119
17.7035
48
A
1555.9681
1035.5445
49
A
1614.7644
0.1878
50
A
1634.7840
19.1540
51
A
3030.8630
30.5026
52
A
3091.5391
27.5588
53
A
3118.2172
35.5822
54
A
3164.7443
2.1491
55
A
3169.4603
0.2489
56
A
3176.3238
14.3686
57
A
3183.3202
39.9408
58
A
3191.1922
18.5837
59
A
3225.9156
24.4370
60
A
3346.5522
21.6791
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
FIREWORKS ENDED AND SPECTATORS GONE AWAY.... AH, HOW VAST AND DARK SHIKI