WebMO Job Summary

254199: BF3, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry BF3
Symmetry D3H
Basis 6-31G(d)
RB3LYP Energy -324.553221908 Hartree
ZPE 0.012555 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -324.537169 Hartree
Enthalpy -324.536225 Hartree
Free Energy -324.565134 Hartree
Cv 10.083 cal/mol-K
Entropy 60.844 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (259546)
CPU time 76.3 sec

Geometry Sequence Energies

Step Energy  
0 -324.468352162  
1 -324.523191118  
2 -324.553163632  
3 -324.553221908  
4 -324.553221908  
5 -324.553221908  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 10.21221 0.34064265886
b 10.21221 0.34064265886
c 5.10611 0.17032149621

Partial Charges

Atom Symbol Charge
1 B 0.646172  
2 F -0.215391  
3 F -0.215391  
4 F -0.215391  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 E' 479.1446 10.7893
2 E' 479.1479 10.7935
3 A2" 684.8513 85.9307
4 A1' 889.2401 0.0000
5 E' 1489.3002 382.3964
6 E' 1489.3471 382.3305
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

... UNTIL SCIENCE IS MIXED WITH EMOTION AND APPEALS TO THE HEART AND IMAGINATION , IT IS LIKE DEAD INORGANIC MATTER; AND WHEN IT IS SO MIXED AND SO TRANSFORMED IT IS LITERATURE. -- JOHN BURROUGHS