WebMO Job Summary

254237: F5Br, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry BrF5
Symmetry C4V
Basis 6-31G(d)
RB3LYP Energy -3070.61505033 Hartree
ZPE 0.011874 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -3070.596572 Hartree
Enthalpy -3070.595628 Hartree
Free Energy -3070.632937 Hartree
Cv 22.539 cal/mol-K
Entropy 78.522 cal/mol-K
Dipole Moment 1.3890 Debye
Server batch (259584)
CPU time 206.8 sec

Geometry Sequence Energies

Step Energy  
0 -3070.60204843  
1 -3070.61336026  
2 -3070.61474240  
3 -3070.61497468  
4 -3070.61505033  
5 -3070.61505033  
6 -3070.61505033  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.95401 0.09853516729
b 2.95401 0.09853516729
c 2.05722 0.06862147279

Partial Charges

Atom Symbol Charge
1 Br 1.604161  
2 F -0.332268  
3 F -0.332268  
4 F -0.275088  
5 F -0.332268  
6 F -0.332268  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 B2 211.2366 0.0000
2 E 225.6052 0.6668
3 E 225.6052 0.6668
4 B1 292.4172 0.0000
5 A1 345.4840 31.0155
6 E 379.0663 4.1433
7 E 379.0663 4.1433
8 B2 558.5696 0.0000
9 A1 587.8199 3.7341
10 E 666.8756 262.1538
11 E 666.8756 262.1538
12 A1 673.4337 40.6866
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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