WebMO Job Summary

254254: C2H2 acetylene, Optimize + Vib Freq - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C2H2
Symmetry D*H
Basis 6-31G(d)
RB3LYP Energy -77.3256461805 Hartree
ZPE 0.026635 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -77.296079 Hartree
Enthalpy -77.295135 Hartree
Free Energy -77.318037 Hartree
Cv 8.707 cal/mol-K
Entropy 48.201 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (259601)
CPU time 55.2 sec

Geometry Sequence Energies

Step Energy  
0 -77.3248359978  
1 -77.3256338674  
2 -77.3256461805  
3 -77.3256461805  
4 -77.3256461805  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 0.0000000 0.00000000000
b 35.2737211 1.17660468630
c 35.2737211 1.17660468630

Partial Charges

Atom Symbol Charge
1 C -0.188313  
2 C -0.188313  
3 H 0.188313  
4 H 0.188313  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 PIG 534.8701 0.0000
2 PIG 534.8701 0.0000
3 PIU 775.2118 81.0599
4 PIU 775.2118 81.0599
5 SGG 2088.1265 0.0000
6 SGU 3441.5738 76.4842
7 SGG 3541.7437 0.0000
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

Where a calculator on the ENIAC is equipped with 18,000 vacuum tubes and weighs 30 tons, computers inthe future may have only 1,000 vacuum tubes and weigh only 1 1/2 tons. ---Popular Mechanics, March 1949