WebMO Job Summary

254257: CH2Cl2 DCM, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry CH2Cl2
Symmetry C2V
Basis 6-31G(d)
RB3LYP Energy -959.696354127 Hartree
ZPE 0.029632 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -959.663152 Hartree
Enthalpy -959.662208 Hartree
Free Energy -959.692897 Hartree
Cv 10.167 cal/mol-K
Entropy 64.590 cal/mol-K
Dipole Moment 1.8525 Debye
Server batch (259604)
CPU time 85.5 sec

Geometry Sequence Energies

Step Energy  
0 -959.694572788  
1 -959.696263266  
2 -959.696348279  
3 -959.696354127  
4 -959.696354127  
5 -959.696354127  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 32.18617 1.07361506739
b 3.19496 0.10657239416
c 2.96195 0.09880001718

Partial Charges

Atom Symbol Charge
1 C -0.444798  
2 Cl -0.019556  
3 Cl -0.019556  
4 H 0.241954  
5 H 0.241954  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A1 283.2887 0.6009
2 A1 704.7318 14.8579
3 B2 728.2758 161.0395
4 B1 914.2364 2.1071
5 A2 1196.3085 0.0000
6 B2 1321.0486 54.9690
7 A1 1489.5683 0.0801
8 A1 3145.1101 8.8136
9 B1 3224.1747 0.4703
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

NOTHING PUZZLES ME MORE THAN TIME AND SPACE; AND YET NOTHING TROUBLES ME LESS -- CHARLES LAMB (1810)