WebMO Job Summary
262096: C6H14OCl(-1) E2 trans Zaitsev TS 2-chlorobutane ethoxide (EtOH), Transition State Optimization - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT=(TS,NoEigenTest,calcFC) SCRF=(PCM,Solvent=ethanol) freq
Method
B3LYP
Stoichiometry
C
6
H
14
ClO(1-)
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-772.719129716 Hartree
ZPE
0.184107 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-772.523113 Hartree
Enthalpy
-772.522169 Hartree
Free Energy
-772.574469 Hartree
C
v
39.656 cal/mol-K
Entropy
110.076 cal/mol-K
Dipole Moment
2.9755 Debye
Server
class (263041)
CPU time
13013.6 sec
Geometry Sequence Energies
Step
Energy (au)
0
-772.706008316
1
-772.718176816
2
-772.719021550
3
-772.719111060
4
-772.719122275
5
-772.719126387
6
-772.719127902
7
-772.719128835
8
-772.719129243
9
-772.719129535
10
-772.719129687
11
-772.719129739
12
-772.719129730
13
-772.719129717
14
-772.719129708
15
-772.719129716
16
-772.719129716
17
-772.719129716
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.63992
0.08805825262
b
0.60537
0.02019296963
c
0.51341
0.01712551421
Partial Charges
Atom
Symbol
Charge
1
C
-0.552990
2
H
0.126037
3
H
0.116169
4
C
-0.434225
5
C
0.527858
6
C
-0.623741
7
H
0.139685
8
H
0.153592
9
H
0.137119
10
H
0.136829
11
H
0.099771
12
H
0.117218
13
H
0.423237
14
O
-0.814852
15
C
0.035108
16
C
-0.375321
17
H
0.098471
18
H
0.101995
19
H
0.096768
20
H
0.048076
21
H
0.044573
22
Cl
-0.601377
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
-607.2123
7181.5797
2
A
39.2349
0.5288
3
A
50.8209
3.9598
4
A
58.0654
2.4191
5
A
85.7913
25.6701
6
A
115.0709
10.8531
7
A
169.9769
1.5611
8
A
184.2367
12.8464
9
A
204.8078
1.0431
10
A
221.0280
3.6923
11
A
258.7114
2.8564
12
A
281.8484
22.6978
13
A
294.6993
2.9172
14
A
427.2039
37.7853
15
A
460.8589
23.8341
16
A
476.4968
14.3879
17
A
795.8189
8.5145
18
A
817.1996
888.0827
19
A
863.9312
0.3067
20
A
873.3003
46.9288
21
A
935.8231
1940.0092
22
A
952.3576
193.3962
23
A
1001.2280
41.9571
24
A
1032.1634
85.5109
25
A
1046.5205
2.4403
26
A
1076.5167
450.1764
27
A
1099.5162
31.8500
28
A
1141.8288
155.3869
29
A
1163.7844
7.3534
30
A
1187.8781
540.5013
31
A
1259.4051
354.4524
32
A
1296.6220
15.6069
33
A
1314.9879
29.3659
34
A
1358.1730
46.2364
35
A
1376.8261
13.2383
36
A
1393.6214
18.5365
37
A
1399.9432
39.0208
38
A
1403.7610
77.6013
39
A
1459.0042
35.5813
40
A
1468.4358
6.0760
41
A
1473.7006
4.8362
42
A
1479.6154
16.8172
43
A
1482.9082
60.9590
44
A
1484.2029
11.7082
45
A
1497.8403
10.4153
46
A
1513.2507
20.9250
47
A
1534.6126
360.6598
48
A
2811.9506
192.7768
49
A
2823.1807
358.8957
50
A
2992.3238
72.9589
51
A
3011.0040
56.8095
52
A
3018.8607
9.2280
53
A
3035.3686
19.7327
54
A
3048.6735
106.2157
55
A
3061.4295
89.5801
56
A
3063.4662
54.9021
57
A
3078.0339
57.7516
58
A
3084.1934
20.6531
59
A
3123.3521
12.6223
60
A
3148.3442
28.4522
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
TWO ROADS DIVERGED IN A WOOD, AND I-- I TOOK THE ONE LESS TRAVELED BY, AND THAT HAS MADE ALL THE DIFFERENCE. -- ROBERT FROST