WebMO Job Summary
262262: C7H6O4N(+1) meta arenium nitration of benzoic acid 2 (H2O), Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT FREQ SCRF=(PCM,Solvent=Water)
Method
B3LYP
Stoichiometry
C
7
H
6
NO
4
(1+)
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-625.877189776 Hartree
ZPE
0.127225 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-625.739701 Hartree
Enthalpy
-625.738757 Hartree
Free Energy
-625.787365 Hartree
C
v
37.777 cal/mol-K
Entropy
102.304 cal/mol-K
Dipole Moment
5.0502 Debye
Server
class (263207)
CPU time
11968 sec
Geometry Sequence Energies
Step
Energy (au)
0
-625.876134491
1
-625.876809514
2
-625.876811166
3
-625.875434269
4
-625.877127926
5
-625.877006220
6
-625.877182768
7
-625.877189488
8
-625.877189854
9
-625.877189831
10
-625.877189776
11
-625.877189776
12
-625.877189776
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.82388
0.06083808820
b
0.60028
0.02002318551
c
0.45917
0.01531626256
Partial Charges
Atom
Symbol
Charge
1
C
-0.165792
2
C
-0.109542
3
C
0.487817
4
C
-0.210416
5
C
-0.304135
6
C
0.244122
7
H
0.199894
8
H
0.168054
9
H
0.196840
10
C
0.635580
11
O
-0.498548
12
O
-0.419373
13
H
0.357932
14
H
0.206893
15
H
0.295300
16
N
0.281037
17
O
-0.172377
18
O
-0.193286
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
36.9136
0.1419
2
A
48.9276
8.9161
3
A
107.0065
6.1388
4
A
136.0485
6.2473
5
A
159.3815
2.4465
6
A
260.1333
3.1673
7
A
321.1357
3.0282
8
A
355.3362
1.3594
9
A
372.3928
9.9597
10
A
428.0241
17.4163
11
A
470.4428
27.1128
12
A
530.0616
8.8435
13
A
575.3924
103.2751
14
A
589.3070
20.0695
15
A
623.0383
70.7947
16
A
658.6121
64.1506
17
A
687.4130
101.1521
18
A
769.4042
24.9121
19
A
780.7337
19.6494
20
A
814.4224
54.0877
21
A
864.7303
76.6325
22
A
924.4197
100.6078
23
A
941.8020
24.5930
24
A
1019.8048
5.2116
25
A
1027.3565
18.9516
26
A
1066.1107
4.4621
27
A
1076.6609
77.8746
28
A
1094.1442
88.3176
29
A
1131.2210
8.1226
30
A
1148.5595
109.1366
31
A
1186.6857
285.5200
32
A
1200.4346
27.7618
33
A
1312.6169
6.5498
34
A
1348.2229
8.1330
35
A
1372.4988
363.6973
36
A
1386.8629
148.8485
37
A
1445.6803
151.7037
38
A
1485.4233
185.7155
39
A
1576.4878
6.8248
40
A
1617.5306
627.4606
41
A
1630.1899
135.2266
42
A
1770.8238
685.1199
43
A
2879.6110
137.0104
44
A
3201.5352
8.3093
45
A
3219.5080
18.7385
46
A
3228.9997
19.9635
47
A
3231.1938
27.5894
48
A
3731.9747
232.1629
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
ONE BIG VICE IN A MAN IS APT TO KEEP OUT MANY SMALLER ONES. -- BRET HARTE