WebMO Job Summary

269283: C7H6O benzadehyde (MeOH), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ SCRF=(PCM,Solvent=Methanol)
Method B3LYP
Stoichiometry C7H6O
Symmetry CS
Basis 6-311+G(2d,p)
RB3LYP Energy -345.685017588 Hartree
ZPE 0.109382 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -345.569297 Hartree
Enthalpy -345.568353 Hartree
Free Energy -345.606237 Hartree
Cv 23.950 cal/mol-K
Entropy 79.735 cal/mol-K
Dipole Moment 4.7338 Debye
Server class (270228)
CPU time 2327.8 sec

Geometry Sequence Energies

Step Energy (au)  
0 -345.671883765  
1 -345.684560282  
2 -345.685002757  
3 -345.685017588  
4 -345.685017588  
5 -345.685017588  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 5.26013 0.17545905041
b 1.56517 0.05220845149
c 1.20625 0.04023616898

Partial Charges

Atom Symbol Charge
1 C -0.146215  
2 C -0.041479  
3 C -0.156564  
4 C -0.469904  
5 C 0.739558  
6 C -0.200454  
7 H 0.123478  
8 C 0.060419  
9 O -0.480835  
10 H 0.109088  
11 H 0.118208  
12 H 0.114215  
13 H 0.116375  
14 H 0.114109  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A" 114.0906 8.7472
2 A' 220.0226 14.2287
3 A" 234.0421 14.3346
4 A" 416.5026 0.2370
5 A' 443.3854 0.6744
6 A" 460.7074 11.8019
7 A' 630.8148 0.5616
8 A' 659.3854 46.8667
9 A" 699.5242 51.9609
10 A" 762.7532 70.9858
11 A' 836.9035 51.2976
12 A" 861.6649 0.0010
13 A" 947.9022 2.0527
14 A" 997.8263 0.0002
15 A' 1017.2728 2.2515
16 A" 1018.4317 0.0595
17 A" 1039.4627 1.6707
18 A' 1040.1752 8.9019
19 A' 1100.1645 8.8373
20 A' 1181.4428 21.9134
21 A' 1185.7003 42.1737
22 A' 1225.3097 120.9790
23 A' 1332.2326 36.5078
24 A' 1352.6863 12.0313
25 A' 1426.3254 11.4339
26 A' 1487.2016 24.1550
27 A' 1523.9568 3.6017
28 A' 1615.1133 46.6081
29 A' 1632.1944 106.8108
30 A' 1720.5155 594.4362
31 A' 2924.4157 151.2935
32 A' 3165.3983 3.7777
33 A' 3172.3248 1.4036
34 A' 3181.6315 12.2669
35 A' 3190.3071 20.6570
36 A' 3195.5367 13.6506
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

0EVERYBODY IS IGNORANT, ONLY ON DIFFERENT SUBJECTS.0 WILL ROGERS