WebMO Job Summary

269297: C7H9N benzyl amine (MeOH), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ SCRF=(PCM,Solvent=Methanol)
Method B3LYP
Stoichiometry C7H9N
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -327.016427903 Hartree
ZPE 0.145415 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -326.863742 Hartree
Enthalpy -326.862798 Hartree
Free Energy -326.903532 Hartree
Cv 27.435 cal/mol-K
Entropy 85.732 cal/mol-K
Dipole Moment 1.7963 Debye
Server class (270242)
CPU time 4916.5 sec

Geometry Sequence Energies

Step Energy (au)  
0 -327.016427862  
1 -327.016428015  
2 -327.016428069  
3 -327.016428060  
4 -327.016428024  
5 -327.016427982  
6 -327.016427925  
7 -327.016427901  
8 -327.016427903  
9 -327.016427903  
10 -327.016427903  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.69695 0.15667338769
b 1.45849 0.04864998972
c 1.19973 0.04001868519

Partial Charges

Atom Symbol Charge
1 C 0.776106  
2 C -0.372977  
3 N -0.532279  
4 H 0.227694  
5 C -0.438512  
6 C -0.136346  
7 C -0.099979  
8 C -0.106234  
9 C -0.295008  
10 H 0.102129  
11 H 0.103624  
12 H 0.102962  
13 H 0.103634  
14 H 0.101355  
15 H 0.105067  
16 H 0.121915  
17 H 0.236850  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A 25.2009 3.0855
2 A 141.2648 6.3632
3 A 242.5676 71.2117
4 A 301.6291 0.7785
5 A 373.0499 16.1502
6 A 416.9015 0.0897
7 A 494.6531 8.6427
8 A 590.0876 15.8187
9 A 636.2319 0.1944
10 A 713.5521 77.5808
11 A 764.1552 57.4086
12 A 799.5642 39.1822
13 A 857.8996 1.9675
14 A 864.7943 129.2648
15 A 934.2192 4.5574
16 A 985.5923 9.8143
17 A 989.2702 44.3710
18 A 1005.6241 0.9527
19 A 1016.8218 3.5121
20 A 1031.7910 22.1414
21 A 1048.7278 2.8533
22 A 1100.9032 4.4569
23 A 1165.6458 1.5312
24 A 1177.1403 0.1719
25 A 1196.8251 0.0858
26 A 1228.6564 4.5694
27 A 1290.0592 4.6766
28 A 1336.9788 0.8700
29 A 1365.7277 1.3455
30 A 1416.7436 32.6970
31 A 1484.8182 9.2728
32 A 1507.7313 3.2628
33 A 1529.2836 8.7328
34 A 1618.9486 0.3941
35 A 1635.3583 12.3446
36 A 1644.8522 31.4789
37 A 2984.8102 102.6730
38 A 3047.6255 36.4304
39 A 3154.6063 10.7008
40 A 3158.7891 2.4423
41 A 3167.6876 13.9361
42 A 3174.8279 53.3304
43 A 3185.3546 19.8827
44 A 3474.8704 0.8033
45 A 3547.7688 2.8200
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

SCIENCE AT ITS BEST PROVIDES US WITH BETTER QUESTIONS, NOT ABSOLUTE ANSWERS -- NORMAN COUSINS, 1976