WebMO Job Summary

30610: CH4 square planar, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry CH4
Symmetry D4H
Basis 6-31G(d)
RB3LYP Energy -40.2785909261 Hartree
ZPE 0.032152 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -40.243598 Hartree
Enthalpy -40.242654 Hartree
Free Energy -40.264051 Hartree
Cv 6.078 cal/mol-K
Entropy 45.034 cal/mol-K
Dipole Moment 0.0000 Debye
Server batch (30786)
CPU time 47.4 sec

Geometry Sequence Energies

Step Energy  
0 -40.2782192332  
1 -40.2785909261  
2 -40.2785909261  
3 -40.2785909261  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 211.30484 7.04837077656
b 211.30484 7.04837077656
c 105.65242 3.52418538828

Partial Charges

Atom Symbol Charge
1 C -1.191954  
2 H 0.297988  
3 H 0.297988  
4 H 0.297988  
5 H 0.297988  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 B2U -6390.2276 0.0000
2 A2U -874.4210 1048.2612
3 EU -498.0509 501.7582
4 EU -498.0509 501.7582
5 B2G 1372.2339 0.0000
6 A1G 2995.1723 0.0000
7 B1G 3039.0658 0.0000
8 EU 3353.3410 254.8590
9 EU 3353.3410 254.8590
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

A DANDELION FROM A LOVER MEANS MORE THAN AN ORCHID FROM A FRIEND.