WebMO Job Summary

323255: AlCl5 EAS electrophile, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry AlCl5
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -2543.58882821 Hartree
ZPE 0.006723 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -2543.572670 Hartree
Enthalpy -2543.571726 Hartree
Free Energy -2543.620813 Hartree
Cv 26.308 cal/mol-K
Entropy 103.312 cal/mol-K
Dipole Moment 2.5324 Debye
Server batch (331008)
CPU time 51.6 sec

Geometry Sequence Energies

Step Energy  
0 -2543.58882821  
1 -2543.58882821  
2 -2543.58882821  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.03252 0.03444115996
b 0.64513 0.02151922047
c 0.61937 0.02065995936

Partial Charges

Atom Symbol Charge
1 Al 0.564274  
2 Cl -0.220423  
3 Cl -0.213091  
4 Cl -0.213091  
5 Cl 0.034132  
6 Cl 0.048199  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 37.5855 0.0186
2 A' 46.6913 1.0471
3 A" 89.9766 0.0322
4 A' 92.1030 1.1172
5 A' 135.0024 2.7672
6 A" 148.8682 6.7414
7 A' 171.5475 2.4712
8 A' 197.5642 97.3547
9 A' 370.5266 10.9267
10 A' 478.2495 13.0791
11 A' 584.0459 154.6982
12 A" 598.8580 177.9681
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THE HURRIEDER I GO, THE BEHINDER I GET.