WebMO Job Summary
324167: Cyclohexanone, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
10
O
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-309.891254504 Hartree
ZPE
0.151701 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-309.733080 Hartree
Enthalpy
-309.732136 Hartree
Free Energy
-309.769951 Hartree
C
v
24.732 cal/mol-K
Entropy
79.587 cal/mol-K
Dipole Moment
3.0738 Debye
Server
batch (331920)
CPU time
562.5 sec
Geometry Sequence Energies
Step
Energy
0
-309.888425525
1
-309.891051347
2
-309.890640684
3
-309.891213826
4
-309.891250459
5
-309.891252850
6
-309.891254262
7
-309.891254499
8
-309.891254504
9
-309.891254504
10
-309.891254504
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
4.18654
0.13964794271
b
2.47173
0.08244803810
c
1.73043
0.05772093173
Partial Charges
Atom
Symbol
Charge
1
C
-0.269902
2
C
-0.261931
3
C
-0.269902
4
C
-0.342315
5
C
0.451695
6
C
-0.342316
7
H
0.163024
8
H
0.152650
9
O
-0.445652
10
H
0.152650
11
H
0.163024
12
H
0.142938
13
H
0.144862
14
H
0.132575
15
H
0.140802
16
H
0.144862
17
H
0.142938
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
94.5809
2.6134
2
A
182.1179
0.8738
3
A
306.9381
0.1988
4
A
403.9902
1.2407
5
A
413.7253
2.4471
6
A
477.0691
0.2849
7
A
489.6095
9.7779
8
A
655.4672
1.4910
9
A
752.0189
3.2411
10
A
768.1738
4.3839
11
A
844.0072
0.1345
12
A
883.1302
3.3878
13
A
902.5475
3.0734
14
A
926.3387
2.8573
15
A
1006.6671
0.7700
16
A
1031.6793
2.6474
17
A
1072.9111
7.9673
18
A
1086.2254
0.4436
19
A
1143.3216
22.6534
20
A
1147.5776
0.4598
21
A
1248.7942
30.9348
22
A
1261.9615
0.5161
23
A
1284.5226
0.1688
24
A
1301.4876
0.1731
25
A
1353.0152
10.9765
26
A
1362.5812
2.1369
27
A
1383.9585
8.1140
28
A
1397.3891
7.6805
29
A
1398.9659
0.2263
30
A
1490.1014
5.7663
31
A
1497.9681
6.9545
32
A
1518.6436
7.3092
33
A
1519.6149
3.7445
34
A
1535.3378
1.0293
35
A
1818.2319
184.0878
36
A
3017.3362
2.1077
37
A
3024.0193
13.1024
38
A
3024.8667
17.3586
39
A
3037.7089
20.3538
40
A
3040.0768
42.5559
41
A
3079.3868
50.3371
42
A
3081.8025
38.8809
43
A
3086.5838
54.9186
44
A
3117.7012
22.4038
45
A
3119.0145
17.7320
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
WHAT THE SLIME CONTAINS, THE GLOWING REVEALS BY THE FLAME'S BRIGHT HUE WHEN YOU IGNITE IT. -- LEONARD THURNEYSSER, 1531-1596 DESCRIBING HIS FLAME PHOTOLYSIS ANALYTIC METHOD