WebMO Job Summary

324169: Ethyl Propionate, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C5H10O2
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -347.022137464 Hartree
ZPE 0.147647 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -346.865837 Hartree
Enthalpy -346.864893 Hartree
Free Energy -346.908683 Hartree
Cv 29.060 cal/mol-K
Entropy 92.165 cal/mol-K
Dipole Moment 1.8367 Debye
Server batch (331922)
CPU time 576.9 sec

Geometry Sequence Energies

Step Energy  
0 -346.991994173  
1 -347.019045243  
2 -347.021862942  
3 -347.022007260  
4 -347.021667857  
5 -347.022068341  
6 -347.021000132  
7 -347.022082488  
8 -347.022119564  
9 -347.022127007  
10 -347.022135845  
11 -347.022137393  
12 -347.022137464  
13 -347.022137464  
14 -347.022137464  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 7.85506 0.26201659816
b 1.25789 0.04195869397
c 1.11420 0.03716571149

Partial Charges

Atom Symbol Charge
1 C -0.031174  
2 C -0.460002  
3 H 0.160751  
4 H 0.152055  
5 H 0.160750  
6 O -0.464511  
7 C 0.623294  
8 C -0.352952  
9 C -0.434842  
10 H 0.141949  
11 H 0.162003  
12 H 0.162040  
13 H 0.171243  
14 H 0.171258  
15 O -0.478345  
16 H 0.158245  
17 H 0.158236  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 30.8967 0.0142
2 A 66.9875 0.1815
3 A 133.1330 3.7299
4 A 152.3609 1.8912
5 A 220.2181 0.7403
6 A 266.1947 1.3038
7 A 287.2900 7.7637
8 A 360.8268 7.8781
9 A 455.3719 4.0331
10 A 577.1654 2.6989
11 A 668.5997 2.1079
12 A 815.0951 8.1990
13 A 822.1458 3.0240
14 A 882.6975 10.6062
15 A 913.4448 2.5701
16 A 1019.9082 0.5540
17 A 1059.4146 29.4818
18 A 1113.3516 22.7878
19 A 1119.6272 0.3491
20 A 1149.4846 15.8538
21 A 1193.2643 4.3696
22 A 1229.7483 477.3582
23 A 1293.4059 0.0340
24 A 1306.0504 0.5293
25 A 1392.0293 65.8541
26 A 1422.2624 17.4869
27 A 1446.1885 2.4410
28 A 1452.4136 4.9716
29 A 1493.1066 10.2205
30 A 1516.7389 5.3397
31 A 1525.4609 5.6242
32 A 1527.1464 3.2551
33 A 1531.2725 8.5211
34 A 1547.4314 4.9300
35 A 1823.8551 200.0886
36 A 3052.8966 13.1189
37 A 3060.9749 18.6570
38 A 3066.6454 22.4630
39 A 3072.4816 17.2238
40 A 3082.5314 6.7999
41 A 3110.1044 7.1176
42 A 3131.4607 25.9362
43 A 3134.9083 26.1714
44 A 3140.5517 36.9533
45 A 3142.5707 28.8054
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

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