WebMO Job Summary
324309: Tert-Butyl Formate, Optimize + Vib Freq - Gaussian
Raw Output
Save Notes
Calculated Quantities
Expand all
Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
5
H
10
O
2
Symmetry
CS
Basis
6-31G(d)
RB3LYP Energy
-347.007932187 Hartree
ZPE
0.146780 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-346.853744 Hartree
Enthalpy
-346.852800 Hartree
Free Energy
-346.891936 Hartree
C
v
27.927 cal/mol-K
Entropy
82.370 cal/mol-K
Dipole Moment
2.4163 Debye
Server
batch (332063)
CPU time
392.3 sec
Geometry Sequence Energies
Step
Energy
0
-346.956395871
1
-346.985987826
2
-347.005029030
3
-347.006994075
4
-347.007866035
5
-347.007924063
6
-347.007931731
7
-347.007932187
8
-347.007932187
9
-347.007932187
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
4.04139
0.13480625987
b
1.90997
0.06370974149
c
1.82179
0.06076837330
Partial Charges
Atom
Symbol
Charge
1
C
0.283897
2
C
-0.442627
3
H
0.168115
4
H
0.168115
5
H
0.136773
6
C
-0.440199
7
H
0.156762
8
H
0.147070
9
H
0.155867
10
C
-0.440199
11
H
0.156762
12
H
0.155867
13
H
0.147070
14
O
-0.441850
15
C
0.380260
16
O
-0.419421
17
H
0.127741
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A"
-70.9482
1.2537
2
A"
217.6025
7.0394
3
A"
229.8230
2.1448
4
A'
239.1524
7.3897
5
A'
282.2879
1.9000
6
A'
307.3755
0.0648
7
A"
319.7269
0.0681
8
A"
352.9391
2.4773
9
A'
412.3312
0.2668
10
A'
434.2313
1.9064
11
A"
470.2018
8.7072
12
A'
684.1738
6.1512
13
A'
802.5642
19.6278
14
A'
837.7628
9.0301
15
A"
934.1128
0.0604
16
A'
935.9795
0.7700
17
A"
982.3562
0.0050
18
A"
1033.4420
0.6254
19
A"
1066.8819
0.9212
20
A'
1073.7983
6.7105
21
A'
1209.0018
312.3607
22
A'
1247.9088
161.9769
23
A"
1282.1793
18.9742
24
A'
1292.8447
16.8956
25
A"
1427.9463
10.2375
26
A'
1435.4947
11.5788
27
A'
1441.1248
0.2758
28
A'
1461.9265
7.6917
29
A"
1502.7546
0.0539
30
A'
1507.7302
1.3038
31
A"
1515.5246
0.1648
32
A'
1527.5233
4.2633
33
A"
1531.4464
2.7888
34
A'
1544.4270
8.3903
35
A'
1823.9840
347.4681
36
A'
3032.2456
95.7022
37
A"
3055.9269
18.2863
38
A'
3058.1396
8.7654
39
A'
3066.1004
18.5968
40
A"
3127.5086
7.6334
41
A'
3130.4752
19.4489
42
A"
3133.9407
6.5544
43
A'
3138.4952
39.7154
44
A'
3143.3183
33.2818
45
A"
3174.3958
14.9639
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
CONTRAIWISE...CONTINUED TWEEDLEDEE, IF IT WAS SO, IT MIGHT BE, AND IF IT WERE SO, IT WOULD BE..... BUT AS IT ISN'T, IT AIN'T.... THAT'S LOGIC..... ALICE THROUGH THE LOOKING GLASS