WebMO Job Summary

324317: Acrolein, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C3H4O
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -191.911973191 Hartree
ZPE 0.061660 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -191.845961 Hartree
Enthalpy -191.845016 Hartree
Free Energy -191.876591 Hartree
Cv 13.700 cal/mol-K
Entropy 66.453 cal/mol-K
Dipole Moment 3.1614 Debye
Server batch (332071)
CPU time 44.3 sec

Geometry Sequence Energies

Step Energy  
0 -191.908913503  
1 -191.911820837  
2 -191.911962534  
3 -191.911973191  
4 -191.911973191  
5 -191.911973191  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 47.99734 1.60101892890
b 4.62884 0.15440148264
c 4.22170 0.14082075407

Partial Charges

Atom Symbol Charge
1 C 0.230484  
2 O -0.402419  
3 C -0.098797  
4 C -0.322219  
5 H 0.163132  
6 H 0.168878  
7 H 0.158739  
8 H 0.102203  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 174.5425 3.9719
2 A' 321.8833 9.3751
3 A' 572.8920 5.8770
4 A" 611.1363 7.2827
5 A' 930.2462 21.4762
6 A" 992.3640 36.2153
7 A" 1023.8006 8.0800
8 A" 1044.3975 7.9622
9 A' 1181.8024 36.5577
10 A' 1309.4886 2.3254
11 A' 1411.1225 6.0216
12 A' 1475.8777 9.6696
13 A' 1701.6959 2.3527
14 A' 1804.2836 211.3088
15 A' 2899.4408 106.3355
16 A' 3162.4575 6.2992
17 A' 3197.1756 2.7680
18 A' 3250.9457 7.8453
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

There was a great rattling of the words for the fewness of ideas. -- Charles Baxter in Gryphon