WebMO Job Summary
335214: 2-Pentanone, Optimize + Vib Freq - Gaussian
Raw Output
Save Notes
Calculated Quantities
Expand all
Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
5
H
10
O
Symmetry
CS
Basis
6-31G(d)
RB3LYP Energy
-271.784149738 Hartree
ZPE
0.141445 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-271.635627 Hartree
Enthalpy
-271.634683 Hartree
Free Energy
-271.673947 Hartree
C
v
24.398 cal/mol-K
Entropy
82.640 cal/mol-K
Dipole Moment
2.6193 Debye
Server
batch (342971)
CPU time
192.9 sec
Geometry Sequence Energies
Step
Energy
0
-271.775952055
1
-271.783625287
2
-271.784117914
3
-271.784148502
4
-271.784149738
5
-271.784149738
6
-271.784149738
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
8.33386
0.27798764704
b
1.77700
0.05927433972
c
1.51942
0.05068239575
Partial Charges
Atom
Symbol
Charge
1
C
-0.528203
2
C
0.452305
3
C
-0.348873
4
C
-0.239980
5
C
-0.446849
6
H
0.147714
7
H
0.139990
8
H
0.139990
9
H
0.150563
10
H
0.150563
11
H
0.153233
12
H
0.153233
13
O
-0.435707
14
H
0.179229
15
H
0.166397
16
H
0.166397
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A"
-28.5976
0.4767
2
A"
83.4448
0.5445
3
A"
94.6877
0.0900
4
A'
172.9814
4.5582
5
A"
246.0711
0.0450
6
A'
339.9978
2.8546
7
A'
392.3041
1.1168
8
A"
474.6870
0.0670
9
A'
593.5572
12.0694
10
A"
731.3669
3.8290
11
A'
825.8010
0.9384
12
A"
843.5838
0.4633
13
A'
909.8395
9.7692
14
A'
969.3434
4.8520
15
A"
987.6199
1.1915
16
A'
1057.4336
0.1473
17
A'
1138.3490
0.1343
18
A"
1153.7478
1.2528
19
A'
1193.7674
73.7271
20
A"
1265.4619
0.0004
21
A"
1337.1696
0.1185
22
A'
1337.9545
13.5403
23
A'
1408.9498
16.9377
24
A'
1419.2142
41.1925
25
A'
1439.4828
1.2485
26
A'
1482.4170
2.6286
27
A'
1495.8982
16.5343
28
A"
1504.9251
10.4774
29
A'
1517.4158
2.5812
30
A"
1529.7561
5.7124
31
A'
1536.7617
4.2177
32
A'
1814.9745
129.9238
33
A'
3014.0707
14.0134
34
A"
3039.5210
9.8058
35
A'
3040.1569
28.4304
36
A'
3048.6904
6.3990
37
A'
3062.9799
20.0423
38
A"
3087.2253
0.4192
39
A"
3105.4041
7.2774
40
A"
3111.9863
70.5786
41
A'
3113.9733
40.8484
42
A'
3164.1572
11.5037
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
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