WebMO Job Summary
379061: C6H15O(+1) protonated 3-methyl-3-pentanol, Optimize + Vib Freq - Gaussian
Raw Output
Save Notes
Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
15
O(1+)
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-312.623658406 Hartree
ZPE
0.205132 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-312.408389 Hartree
Enthalpy
-312.407445 Hartree
Free Energy
-312.452340 Hartree
C
v
37.255 cal/mol-K
Entropy
94.491 cal/mol-K
Dipole Moment
2.6813 Debye
Server
batch (390245)
CPU time
1635.7 sec
Geometry Sequence Energies
Step
Energy
0
-312.579624570
1
-312.605679907
2
-312.620709474
3
-312.622194860
4
-312.622925554
5
-312.623501908
6
-312.623596165
7
-312.623620816
8
-312.623633794
9
-312.623637162
10
-312.623642432
11
-312.623649549
12
-312.623657879
13
-312.623658720
14
-312.623658406
15
-312.623658406
16
-312.623658406
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
3.97635
0.13263675899
b
1.54564
0.05155700081
c
1.53395
0.05116706438
Partial Charges
Atom
Symbol
Charge
1
C
-0.465831
2
C
-0.302852
3
C
0.211128
4
C
-0.296785
5
C
-0.483121
6
H
0.216629
7
H
0.134318
8
H
0.194495
9
H
0.213665
10
H
0.177379
11
C
-0.488755
12
H
0.190578
13
H
0.218234
14
H
0.221309
15
O
-0.638677
16
H
0.481731
17
H
0.480643
18
H
0.211533
19
H
0.169527
20
H
0.200947
21
H
0.184441
22
H
0.169464
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
86.6450
1.4520
2
A
101.0540
1.2233
3
A
173.3702
51.9163
4
A
187.8859
3.4744
5
A
216.9701
4.4680
6
A
241.8880
0.3860
7
A
253.2178
5.3557
8
A
300.2384
2.7703
9
A
333.6143
39.9962
10
A
336.0822
0.0979
11
A
350.3503
5.1223
12
A
410.0806
2.9524
13
A
449.5097
31.8419
14
A
522.3279
21.4946
15
A
720.8296
245.0281
16
A
750.6980
9.8857
17
A
772.1680
33.7365
18
A
797.4706
8.9710
19
A
860.7997
2.1329
20
A
921.8443
9.4868
21
A
970.5983
12.1691
22
A
1007.3772
2.3333
23
A
1023.9912
5.6502
24
A
1061.5562
1.9562
25
A
1101.5261
5.0833
26
A
1109.2306
0.6592
27
A
1156.8473
26.0102
28
A
1220.4796
37.5093
29
A
1276.7728
9.0410
30
A
1291.7875
3.3180
31
A
1355.2376
3.0271
32
A
1404.1534
4.6979
33
A
1408.5515
1.2966
34
A
1444.9430
28.1620
35
A
1454.8971
6.6434
36
A
1460.1578
1.1455
37
A
1485.4894
0.2939
38
A
1504.7768
3.6723
39
A
1508.7993
4.2031
40
A
1521.2206
13.6912
41
A
1522.9815
28.7416
42
A
1529.8470
10.3116
43
A
1538.8061
6.5157
44
A
1547.6416
12.6692
45
A
1680.2396
107.2961
46
A
3037.6768
24.5648
47
A
3039.5465
12.5192
48
A
3052.9237
10.3221
49
A
3070.8539
2.9567
50
A
3075.4228
2.7129
51
A
3076.0317
8.2084
52
A
3087.9197
5.8619
53
A
3124.9511
10.9777
54
A
3142.2199
2.8654
55
A
3145.6227
10.9309
56
A
3152.8312
7.1472
57
A
3158.1174
8.0151
58
A
3177.7066
2.0673
59
A
3612.4798
112.9059
60
A
3713.2733
157.3088
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
QED = W**5 (WHICH WAS WHAT WE WANTED)