WebMO Job Summary

379136: H2O4P(-1) dihydrogen phosphate, Optimize + Vib Freq 12 proc + 10 - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry H2O4P(1-)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -643.586213726 Hartree
ZPE 0.036698 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -643.543805 Hartree
Enthalpy -643.542860 Hartree
Free Energy -643.578544 Hartree
Cv 19.203 cal/mol-K
Entropy 75.102 cal/mol-K
Dipole Moment 3.5823 Debye
Server batch (390320)
CPU time 478.6 sec

Geometry Sequence Energies

Step Energy  
0 -643.444885065  
1 -643.509866325  
2 -643.581607450  
3 -643.583359080  
4 -643.583824056  
5 -643.584482417  
6 -643.584776740  
7 -643.585396995  
8 -643.585735795  
9 -643.586036832  
10 -643.586178124  
11 -643.586198522  
12 -643.586214681  
13 -643.586215339  
14 -643.586214165  
15 -643.586213726  
16 -643.586213726  
17 -643.586213726  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.59436 0.15325135364
b 4.57582 0.15263292581
c 4.24741 0.14167834736

Partial Charges

Atom Symbol Charge
1 P 1.010387  
2 O -0.703005  
3 H 0.375925  
4 O -0.702908  
5 H 0.375927  
6 O -0.635636  
7 O -0.720691  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 131.6067 24.5128
2 A 297.9133 15.3380
3 A 321.2589 88.5937
4 A 354.7434 24.6893
5 A 417.3746 9.8246
6 A 480.7096 53.2980
7 A 494.6848 59.3871
8 A 745.8238 100.3361
9 A 791.9118 350.5675
10 A 1047.8273 121.0902
11 A 1052.8656 11.5555
12 A 1115.6465 260.7635
13 A 1336.2649 270.5118
14 A 3759.1095 12.3360
15 A 3760.8128 19.4216
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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