WebMO Job Summary
379180: C2H4O2 trichloroacetic acid Cs, Optimize + Vib Freq 12 proc + 10 - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
2
HCl
3
O
2
Symmetry
CS
Basis
6-31G(d)
RB3LYP Energy
-1607.8281294 Hartree
ZPE
0.033551 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-1607.787162 Hartree
Enthalpy
-1607.786218 Hartree
Free Energy
-1607.828234 Hartree
C
v
24.534 cal/mol-K
Entropy
88.430 cal/mol-K
Dipole Moment
1.9393 Debye
Server
batch (390364)
CPU time
291.3 sec
Geometry Sequence Energies
Step
Energy
0
-1607.82548080
1
-1607.82779021
2
-1607.82810311
3
-1607.82812840
4
-1607.82812940
5
-1607.82812940
6
-1607.82812940
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.48221
0.04944120375
b
1.36886
0.04566025474
c
1.24520
0.04153540113
Partial Charges
Atom
Symbol
Charge
1
C
-0.359755
2
C
0.623661
3
O
-0.396395
4
O
-0.526767
5
H
0.432388
6
Cl
0.067321
7
Cl
0.092226
8
Cl
0.067321
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A"
36.9696
1.4402
2
A"
185.4001
0.0789
3
A'
190.5063
1.0858
4
A'
270.6638
0.4143
5
A"
280.5543
0.3235
6
A'
291.3317
0.0733
7
A'
414.9213
0.5282
8
A'
428.3646
1.8347
9
A"
561.7468
21.4204
10
A'
651.8290
100.2578
11
A"
689.0693
247.2814
12
A"
823.1329
40.9778
13
A'
826.1636
189.1689
14
A'
938.9038
11.5833
15
A'
1188.4722
197.5836
16
A'
1380.9175
45.4404
17
A'
1872.9779
232.6839
18
A'
3695.1978
89.0975
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
Any fool can criticize, condemn, and complain -- and most do. -- Dale Carnegie