WebMO Job Summary

379183: C4H10O (R)-2-butanol, Optimize + Vib Freq 12 proc + 10 - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C4H10O
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -233.666924674 Hartree
ZPE 0.137151 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -233.523029 Hartree
Enthalpy -233.522085 Hartree
Free Energy -233.559401 Hartree
Cv 23.729 cal/mol-K
Entropy 78.538 cal/mol-K
Dipole Moment 1.5812 Debye
Server batch (390367)
CPU time 470.6 sec

Geometry Sequence Energies

Step Energy  
0 -233.663250904  
1 -233.666766451  
2 -233.666892835  
3 -233.666912496  
4 -233.666919404  
5 -233.666922486  
6 -233.666924441  
7 -233.666924674  
8 -233.666924674  
9 -233.666924674  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 8.11054 0.27053849367
b 3.41201 0.11381240285
c 2.64374 0.08818567410

Partial Charges

Atom Symbol Charge
1 C -0.443302  
2 C 0.141345  
3 C -0.248771  
4 C -0.465092  
5 H 0.152494  
6 H 0.142377  
7 H 0.137851  
8 H 0.140381  
9 H 0.128941  
10 H 0.105001  
11 O -0.627269  
12 H 0.390718  
13 H 0.155151  
14 H 0.137903  
15 H 0.152273  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 105.7922 1.3770
2 A 225.0635 0.8911
3 A 232.5243 16.9910
4 A 248.4530 4.2528
5 A 315.9272 102.9934
6 A 377.5037 9.4397
7 A 465.7618 4.5640
8 A 488.7676 9.1628
9 A 775.7776 0.7606
10 A 828.7958 2.8882
11 A 934.1528 19.6536
12 A 992.5167 6.9257
13 A 1017.3353 8.0443
14 A 1029.6936 42.4490
15 A 1095.4426 6.6314
16 A 1169.4251 11.4880
17 A 1199.1761 17.0545
18 A 1287.9008 56.9976
19 A 1315.2206 7.0658
20 A 1349.7291 15.2106
21 A 1410.0997 9.9954
22 A 1424.6202 7.1256
23 A 1435.2651 6.6809
24 A 1457.4821 12.5019
25 A 1505.2372 0.5311
26 A 1515.9242 4.0211
27 A 1529.8032 5.0920
28 A 1531.0532 2.2278
29 A 1542.0351 5.8838
30 A 2961.0089 60.1279
31 A 3035.8595 8.4430
32 A 3038.4935 41.6642
33 A 3056.2363 22.1101
34 A 3072.2849 7.1667
35 A 3102.0370 56.0508
36 A 3115.9175 30.7994
37 A 3125.5173 39.6624
38 A 3134.3706 28.1401
39 A 3754.3343 7.1291
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

CHRISTMAS IS ON TOP OF A STEEP HILL. THE CLOSER YOU GET, THE STEEPER THE HILL IS. -- LINUS, OF PEANUTS