WebMO Job Summary

379185: C3H4 propyne, Optimize + Vib Freq 12 proc + 10 - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C3H4
Symmetry C3V
Basis 6-31G(d)
RB3LYP Energy -116.653270051 Hartree
ZPE 0.055717 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -116.593555 Hartree
Enthalpy -116.592611 Hartree
Free Energy -116.620744 Hartree
Cv 12.468 cal/mol-K
Entropy 59.211 cal/mol-K
Dipole Moment 0.6867 Debye
Server batch (390369)
CPU time 92.4 sec

Geometry Sequence Energies

Step Energy  
0 -116.649408099  
1 -116.653029620  
2 -116.653261818  
3 -116.653270051  
4 -116.653270051  
5 -116.653270051  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 159.93732 5.33493474342
b 8.52407 0.28433236970
c 8.52407 0.28433236970

Partial Charges

Atom Symbol Charge
1 C -0.574854  
2 C 0.304710  
3 C -0.460624  
4 H 0.183426  
5 H 0.182447  
6 H 0.182447  
7 H 0.182447  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 E 346.6583 2.8158
2 E 346.6593 2.8156
3 E 600.0181 50.0953
4 E 600.0182 50.0957
5 A1 950.9373 0.8792
6 E 1075.2781 1.7796
7 E 1075.2795 1.7798
8 A1 1445.5950 0.6480
9 E 1508.5653 6.3292
10 E 1508.5656 6.3297
11 A1 2248.3904 2.7845
12 A1 3043.4022 20.1842
13 E 3105.4612 12.1507
14 E 3105.4614 12.1484
15 A1 3496.5805 51.1145
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IT PROBABLY IS NOT POSSIBLE FOR A SCIENTIST TO INTERROGATE NATURE FROM A WHOLLY DISINTERESTED VIEWPOINT. EVEN IF HE HAS NO PARTICULAR AXE TO GRIND, HE IS LIKELY TO HAVE A DISTINCTIVE WAY OF VIEWING NATURE. -- JOHN LOSEE