WebMO Job Summary

379200: C2H6S ethanethiol, Optimize + Vib Freq 12 proc + 10 - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C2H6S
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -478.012895503 Hartree
ZPE 0.075332 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -477.932819 Hartree
Enthalpy -477.931875 Hartree
Free Energy -477.964442 Hartree
Cv 14.898 cal/mol-K
Entropy 68.543 cal/mol-K
Dipole Moment 1.7999 Debye
Server batch (390384)
CPU time 405.8 sec

Geometry Sequence Energies

Step Energy  
0 -478.012894093  
1 -478.012895503  
2 -478.012895503  
3 -478.012895503  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 28.54705 0.95222709038
b 5.35637 0.17866927126
c 4.78096 0.15947565966

Partial Charges

Atom Symbol Charge
1 C -0.451598  
2 C -0.388920  
3 S -0.088257  
4 H 0.089049  
5 H 0.175143  
6 H 0.175143  
7 H 0.156455  
8 H 0.166493  
9 H 0.166493  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 161.4361 20.5152
2 A" 258.2667 0.8719
3 A' 302.3342 2.7377
4 A' 666.0840 1.9605
5 A" 800.7592 4.2921
6 A' 866.1640 2.5052
7 A' 1002.1756 3.6896
8 A" 1062.0296 0.3704
9 A' 1125.2408 2.1126
10 A" 1286.7702 0.5719
11 A' 1326.4219 48.2124
12 A' 1443.6247 2.9622
13 A' 1519.8779 3.4076
14 A" 1524.9183 7.3522
15 A' 1535.0465 1.9028
16 A' 2674.5605 27.1063
17 A' 3056.5005 20.5179
18 A' 3075.4268 23.9359
19 A" 3115.8539 0.0539
20 A' 3124.2162 26.2929
21 A" 3139.2023 35.4960
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

YOU KNOW YOU'VE SPOKEN TOO LONG WHEN THE AUDIENCE STOPS LOOKING AT THEIR WATCHES AND STARTS SHAKING THEM.