WebMO Job Summary
385190: C8H18O (3S,4S)-3,4-dimethyl-3-hexanol, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
8
H
18
O
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-390.916085219 Hartree
ZPE
0.251083 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-390.653040 Hartree
Enthalpy
-390.652095 Hartree
Free Energy
-390.702194 Hartree
C
v
44.639 cal/mol-K
Entropy
105.442 cal/mol-K
Dipole Moment
1.4141 Debye
Server
batch (396375)
CPU time
3708.4 sec
Geometry Sequence Energies
Step
Energy
0
-390.909332157
1
-390.915617731
2
-390.915568152
3
-390.915875543
4
-390.915940672
5
-390.916020468
6
-390.916042434
7
-390.916059264
8
-390.916078089
9
-390.916085462
10
-390.916087537
11
-390.916086657
12
-390.916087079
13
-390.916086095
14
-390.916085284
15
-390.916083926
16
-390.916085941
17
-390.916087508
18
-390.916088421
19
-390.916086704
20
-390.916085441
21
-390.916085593
22
-390.916085313
23
-390.916085456
24
-390.916084222
25
-390.916084791
26
-390.916085411
27
-390.916085219
28
-390.916085219
29
-390.916085219
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.76968
0.09238658032
b
0.92948
0.03100411552
c
0.83873
0.02797702136
Partial Charges
Atom
Symbol
Charge
1
C
-0.465834
2
C
0.312814
3
C
-0.062694
4
C
-0.260360
5
C
-0.452056
6
H
0.142340
7
H
0.138208
8
H
0.145280
9
H
0.145706
10
H
0.135675
11
H
0.112370
12
C
-0.492527
13
H
0.156074
14
H
0.144300
15
H
0.140711
16
C
-0.280472
17
H
0.123934
18
H
0.131128
19
C
-0.448189
20
H
0.138221
21
H
0.146243
22
H
0.155612
23
O
-0.646844
24
H
0.388998
25
H
0.154593
26
H
0.135773
27
H
0.160994
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
30.2347
0.2607
2
A
77.1465
0.0098
3
A
103.8144
0.0629
4
A
176.4538
0.7004
5
A
197.6023
1.2230
6
A
220.6672
0.1712
7
A
238.9408
0.0465
8
A
254.0134
4.1968
9
A
295.7315
0.1289
10
A
307.1107
12.4215
11
A
344.4119
8.4651
12
A
357.4101
88.9483
13
A
366.2267
0.0460
14
A
379.6224
14.2973
15
A
388.3403
16.5098
16
A
470.0114
7.2738
17
A
492.2743
1.8701
18
A
613.8774
4.4935
19
A
727.4345
0.4674
20
A
792.0137
0.4754
21
A
800.7172
3.6023
22
A
829.0563
0.5475
23
A
906.7302
3.0310
24
A
929.1448
24.3454
25
A
968.6058
3.3017
26
A
990.2608
24.8479
27
A
1012.7030
3.4756
28
A
1017.5342
7.9863
29
A
1043.5205
6.8234
30
A
1067.9571
1.0424
31
A
1092.3156
8.9132
32
A
1118.0502
10.5581
33
A
1166.5137
22.2728
34
A
1176.7572
19.6248
35
A
1213.2924
7.5990
36
A
1224.8024
18.3326
37
A
1302.5994
7.7702
38
A
1312.4697
12.6840
39
A
1337.3165
17.2002
40
A
1374.2982
3.5804
41
A
1384.0279
5.1379
42
A
1395.5062
15.2636
43
A
1400.9402
0.9069
44
A
1434.0803
10.3031
45
A
1438.0798
3.7347
46
A
1440.4061
3.4071
47
A
1448.8266
4.3942
48
A
1507.8135
0.8257
49
A
1517.3022
1.6539
50
A
1519.4702
1.0848
51
A
1527.6096
5.4426
52
A
1529.2155
3.8253
53
A
1536.3104
2.8040
54
A
1538.2692
7.8095
55
A
1541.6191
6.1529
56
A
1553.6546
5.4723
57
A
1553.9726
0.2848
58
A
3004.8001
15.2271
59
A
3038.1298
22.6960
60
A
3042.0626
21.0990
61
A
3046.0417
33.4125
62
A
3049.2289
17.0993
63
A
3056.8903
27.7861
64
A
3067.3754
6.0094
65
A
3071.6923
31.9678
66
A
3089.7289
11.1427
67
A
3104.8778
41.9807
68
A
3115.9539
14.6506
69
A
3118.2028
41.4816
70
A
3121.9175
74.0020
71
A
3132.6442
37.3927
72
A
3134.6164
28.0532
73
A
3140.9202
24.0233
74
A
3155.6971
23.6292
75
A
3737.0281
5.8049
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
KNOWLEDGE IS EXPERIMENT'S DAUGHTER. -- LEONARDO DA VINCI, IN "PENSIERI" CA. 1492