WebMO Job Summary

385226: C3H7O3N L-serine zwitterion, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry C3H7NO3
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -398.961615189 Hartree
ZPE 0.115616 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -398.839029 Hartree
Enthalpy -398.838085 Hartree
Free Energy -398.877170 Hartree
Cv 24.930 cal/mol-K
Entropy 82.262 cal/mol-K
Dipole Moment 11.6037 Debye
Server batch (396411)
CPU time 871.7 sec

Geometry Sequence Energies

Step Energy  
0 -398.921648705  
1 -398.949567536  
2 -398.936561494  
3 -398.952438166  
4 -398.955917059  
5 -398.957583667  
6 -398.959278485  
7 -398.960368263  
8 -398.961223850  
9 -398.961485508  
10 -398.961599447  
11 -398.961612971  
12 -398.961610825  
13 -398.961615189  
14 -398.961615189  
15 -398.961615189  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.57479 0.11924215919
b 2.47104 0.08242502218
c 1.54375 0.05149395720

Partial Charges

Atom Symbol Charge
1 C -0.139830  
2 C 0.604993  
3 O -0.616343  
4 O -0.612948  
5 C -0.029979  
6 O -0.671768  
7 H 0.415732  
8 H 0.163646  
9 H 0.139482  
10 H 0.215483  
11 N -0.738146  
12 H 0.423418  
13 H 0.429586  
14 H 0.416673  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 82.5524 9.6971
2 A 175.6715 5.0597
3 A 266.8783 36.3414
4 A 293.1166 16.8193
5 A 339.8747 3.9306
6 A 348.8619 77.0257
7 A 417.2119 5.1758
8 A 555.5424 42.4002
9 A 614.5511 7.8814
10 A 716.5185 176.6735
11 A 762.5801 31.0742
12 A 838.6007 73.4810
13 A 953.2380 45.6770
14 A 991.2159 56.5396
15 A 1050.3373 30.2896
16 A 1098.7876 116.4648
17 A 1119.7008 52.5622
18 A 1187.7912 22.8525
19 A 1238.8206 42.8940
20 A 1333.3396 31.1206
21 A 1369.0627 9.9334
22 A 1383.3559 113.9010
23 A 1416.0648 336.8572
24 A 1448.7867 408.4411
25 A 1525.0180 216.1330
26 A 1546.6935 5.9196
27 A 1653.9898 48.5697
28 A 1691.7075 49.0620
29 A 1746.4564 363.3834
30 A 2975.5922 103.8554
31 A 2996.7130 407.5288
32 A 3086.4626 77.1146
33 A 3125.5867 10.3581
34 A 3395.5152 455.8707
35 A 3464.9186 82.2253
36 A 3538.3722 112.7015
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

LET US LEARN TO DREAM, GENTLEMEN, THEN PERHAPS WE SHALL DISCOVER THE TRUTH; BUT LET US BEWARE OF PUBLISHING OUR DREAMS ABROAD BEFORE THEY HAVE BEEN SCRUTINIZED BY OUR VIGILANT INTELLECT ... LET US ALWAYS ALLOW THE FRUIT TO HANG UNTIL IT IS RIPE. UNRIPE FRUIT BRINGS EVEN THE GROWER BUT LITTLE PROFIT; IT DAMAGES THE HEALTH OF THOSE WHO CONSUME IT; IT ENDANGERS PARTICULARLY THE YOUTH WHO CANNOT YET DISTINGUISH BETWEEN RIPE AND UNRIPE FRUIT. -- KEKULE, 1890