WebMO Job Summary
391: C6H13FSi 1-ETHYL-1-FLUOROSILACYCLOPENTANE conformer B C1 29Si, Opt + Ultrafine Anharmonic Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT(maxstep=10,maxcycles=50,VeryTight) FREQ(Anharmonic,vibrot) int=ultrafine
Method
B3LYP
Stoichiometry
C
6
H
13
FSi
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-626.034793616 Hartree
ZPE
0.180025 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-625.844882 Hartree
Enthalpy
-625.843938 Hartree
Free Energy
-625.890124 Hartree
C
v
36.771 cal/mol-K
Entropy
97.207 cal/mol-K
Dipole Moment
1.8859 Debye
Server
batch (119427)
CPU time
628216.4 sec
Geometry Sequence Energies
Step
Energy (au)
0
-626.034857418
1
-626.034857418
2
-626.034857418
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.70622
0.09026978257
b
1.10945
0.03700726854
c
1.08121
0.03606528354
Partial Charges
Atom
Symbol
Charge
1
C
-0.718038
2
Si
1.662841
3
C
-0.680559
4
C
-0.183791
5
C
-0.131485
6
H
0.100095
7
H
0.111654
8
H
0.105078
9
H
0.100213
10
H
0.131972
11
H
0.114431
12
F
-0.530442
13
C
-0.451470
14
C
-0.497162
15
H
0.139257
16
H
0.116737
17
H
0.121671
18
H
0.124018
19
H
0.120655
20
H
0.121408
21
H
0.122919
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
54.4762
0.0636
2
A
74.9982
0.6950
3
A
115.5339
0.3974
4
A
168.8434
1.4909
5
A
205.1596
3.1638
6
A
254.8026
5.1850
7
A
257.1461
0.4009
8
A
276.7382
2.5846
9
A
316.3921
7.0389
10
A
442.5434
19.7201
11
A
495.2716
2.1415
12
A
591.3063
3.6083
13
A
653.9879
9.4237
14
A
701.8887
63.2400
15
A
713.4776
30.9849
16
A
719.4422
10.2136
17
A
785.6669
85.3958
18
A
846.6037
95.2253
19
A
850.8250
14.3328
20
A
864.0511
19.1847
21
A
930.9533
1.1888
22
A
953.9845
1.1564
23
A
973.5674
3.2914
24
A
980.9583
6.2057
25
A
1023.1394
4.9529
26
A
1026.4695
34.4568
27
A
1053.7334
11.7082
28
A
1104.7053
47.7794
29
A
1182.6351
3.5861
30
A
1225.4766
0.3846
31
A
1265.0299
1.4442
32
A
1276.1793
4.7511
33
A
1283.8057
7.7923
34
A
1287.5970
0.8781
35
A
1345.1560
1.5972
36
A
1350.9212
1.0590
37
A
1417.4227
1.1657
38
A
1449.7832
8.3037
39
A
1452.8483
3.5708
40
A
1455.2542
9.4623
41
A
1497.0303
5.2109
42
A
1504.3474
5.3015
43
A
1505.5300
1.9033
44
A
1509.1686
5.9014
45
A
3005.9905
6.2297
46
A
3006.7168
30.6503
47
A
3013.7673
22.4674
48
A
3018.3746
24.0951
49
A
3022.5317
40.0391
50
A
3028.0978
13.9919
51
A
3038.8752
7.4318
52
A
3053.2468
47.5482
53
A
3058.1346
48.4953
54
A
3075.7254
32.5345
55
A
3081.8236
18.4624
56
A
3084.9428
19.0890
57
A
3088.6950
28.3760
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Anharmonic Vibrational Modes
Mode
Frequency (cm
-1
)
IR Intensity
Raman Intensity
1
2965.946
34.19700239
2
2951.293
42.24694539
3
2958.259
19.96393238
4
2943.422
35.68014494
5
2912.935
44.97629515
6
2923.311
53.66633399
7
2894.224
3.63351270
8
2902.231
14.58334020
9
2868.522
31.95769908
10
2894.567
30.03854025
11
2827.613
32.56183459
12
2869.910
9.29852714
13
2863.862
6.87475332
14
1467.116
4.96890850
15
1476.479
0.88943917
16
1455.531
0.64885148
17
1458.230
4.51934008
18
1424.653
4.22807821
19
1417.812
2.96283725
20
1415.824
2.67336950
21
1386.143
1.33428819
22
1317.927
0.98128385
23
1315.165
1.47439079
24
1257.218
0.31379303
25
1254.236
2.17221080
26
1244.356
4.08652560
27
1233.965
1.34909362
28
1198.049
0.22522020
29
1154.133
2.78315958
30
1083.396
17.83110997
31
1036.691
9.62194395
32
1003.360
21.40141773
33
996.200
10.63246208
34
966.259
4.71135523
35
950.830
0.85851969
36
936.267
0.85578448
37
916.384
0.84946296
38
846.843
26.67720362
39
833.130
26.20361646
40
831.203
59.66818385
41
773.253
66.67330343
42
706.731
17.97408249
43
703.652
20.38168468
44
689.368
17.09777629
45
644.579
8.70004648
46
583.034
2.22314205
47
492.135
1.32519094
48
437.524
19.16103509
49
312.814
6.80796541
50
267.943
1.38789976
51
285.316
5.02648116
52
249.596
3.62928517
53
206.451
2.75534417
54
155.003
1.10885778
55
114.326
0.18124409
56
67.736
0.14511366
57
46.072
0.15214076
58
5853.554
0.26254095
59
5802.911
0.47537270
60
5807.544
0.43873196
61
5810.185
0.51108687
62
5843.662
0.01296541
63
5785.971
0.46937636
64
5668.548
0.31877513
65
5738.018
0.41715491
66
5729.338
0.00808003
67
5746.148
0.15587925
68
5700.697
0.50033498
69
5767.499
0.05280154
70
5758.757
0.07477313
71
2950.573
5.59693825
72
2940.905
4.40725581
73
2936.006
6.91570709
74
2921.059
18.12629445
75
2841.755
0.17340005
76
2828.134
1.42326769
77
2818.673
0.63990855
78
2743.750
2.02802118
79
2615.904
0.25099661
80
2629.125
0.10840395
81
2511.125
0.01094498
82
2504.335
0.03174702
83
2479.874
0.00302941
84
2461.875
0.03874571
85
2393.828
0.05570381
86
2304.155
0.00868044
87
2164.446
0.06351819
88
2072.863
0.03871985
89
1995.229
0.01044469
90
1987.958
0.00268267
91
1932.813
0.06495780
92
1914.396
0.06180642
93
1872.316
0.00003828
94
1832.955
0.00948092
95
1692.098
0.03769586
96
1664.210
0.00935070
97
1660.692
0.08715104
98
1544.323
0.17234731
99
1408.564
0.83855659
100
1404.074
0.40837451
101
1383.343
0.14381323
102
1288.179
0.26669431
103
1164.804
0.15611195
104
984.678
0.05633472
105
874.629
0.20066366
106
625.068
0.10319406
107
537.742
0.00683780
108
499.780
0.07341181
109
500.081
0.00214499
110
409.245
0.01060551
111
347.030
0.00739644
112
231.386
0.00981054
113
150.973
0.00170678
114
99.375
0.00164042
115
6173.638
0.00085257
116
6170.519
0.00198720
117
6166.766
0.02911907
118
6164.420
0.23925640
119
6160.668
0.00115345
120
6157.549
0.00355268
121
6146.830
0.00031934
122
6143.077
0.03213512
123
6139.958
0.06022562
124
6133.860
0.00040984
125
6141.942
0.00018504
126
6138.190
0.00478207
127
6135.070
0.00923291
128
6128.972
0.00009961
129
6111.381
0.29521504
130
6127.570
0.09087603
131
6123.818
0.00008224
132
6120.699
0.00033070
133
6114.601
0.05604567
134
6097.010
0.00171972
135
6092.122
0.00175711
136
6116.793
0.00000170
137
6113.041
0.00068928
138
6109.921
0.23071640
139
6103.823
0.00030300
140
6086.232
0.09004175
141
6081.345
0.08667264
142
6066.973
0.00036280
143
6111.227
0.03795101
144
6107.474
0.00171080
145
6104.355
0.00071944
146
6098.257
0.17766519
147
6080.666
0.00151421
148
6075.778
0.00071028
149
6061.407
0.03542906
150
6050.629
0.00111263
151
6107.070
0.00018592
152
6103.317
0.13879802
153
6100.198
0.00673512
154
6094.100
0.00115470
155
6076.509
0.15060460
156
6071.621
0.10212934
157
6057.250
0.01152839
158
6046.472
0.00352531
159
6040.906
0.00015070
160
6102.462
0.00010471
161
6098.710
0.04451349
162
6095.591
0.01343495
163
6089.493
0.00028103
164
6071.902
0.10410965
165
6067.014
0.27242473
166
6052.642
0.00045962
167
6041.865
0.02358701
168
6036.299
0.00025899
169
6032.142
0.17410557
170
6095.412
0.00568286
171
6091.660
0.00398349
172
6088.540
0.02850340
173
6082.442
0.02486194
174
6064.851
0.12215388
175
6059.964
0.03997079
176
6045.592
0.24242941
177
6034.815
0.00399990
178
6029.248
0.02459383
179
6025.091
0.00317897
180
6020.484
0.07316404
181
6094.685
0.00385989
182
6090.933
0.00878212
183
6087.814
0.01286849
184
6081.716
0.01417508
185
6064.125
0.14616776
186
6059.237
0.05624270
187
6044.866
0.21328784
188
6034.088
0.00120265
189
6028.522
0.01788300
190
6024.365
0.02584326
191
6019.758
0.08104526
192
6012.707
0.02651064
193
4597.864
0.18262336
194
4594.111
0.00109451
195
4590.992
0.00015185
196
4584.894
0.14898726
197
4567.303
0.00111078
198
4562.415
0.00127004
199
4548.044
0.03106029
200
4537.266
0.00028437
201
4531.700
0.17121361
202
4527.543
0.00161424
203
4522.936
0.00051346
204
4515.885
0.00309273
205
4515.159
0.00451515
206
4594.225
0.00782196
207
4590.473
0.01312644
208
4587.354
0.01243803
209
4581.255
0.01722843
210
4563.665
0.14061083
211
4558.777
0.18116015
212
4544.405
0.00295995
213
4533.628
0.01957217
214
4528.062
0.01215381
215
4523.905
0.05381516
216
4519.297
0.13226555
217
4512.247
0.00862504
218
4511.520
0.01719102
219
3014.699
10.40878383
220
4593.042
0.15107049
221
4589.290
0.00199735
222
4586.171
0.00157989
223
4580.073
0.26268765
224
4562.482
0.00836897
225
4557.594
0.00838322
226
4543.223
0.03128989
227
4532.445
0.00178563
228
4526.879
0.18107890
229
4522.722
0.00133396
230
4518.115
0.00544884
231
4511.064
0.00774481
232
4510.338
0.00173148
233
3013.516
4.92218293
234
3009.877
9.97083534
235
4585.725
0.00020836
236
4581.973
0.00392951
237
4578.854
0.00545986
238
4572.756
0.00035768
239
4555.165
0.12501342
240
4550.277
0.21007101
241
4535.905
0.00073713
242
4525.128
0.04343187
243
4519.562
0.00026503
244
4515.405
0.09766122
245
4510.798
0.23242015
246
4503.747
0.15468407
247
4503.021
0.20683777
248
3006.199
51.81528286
249
3002.560
10.61086784
250
3001.378
8.12076366
251
4543.949
0.00046706
252
4540.197
0.04606064
253
4537.078
0.09053556
254
4530.980
0.00249168
255
4513.389
0.00103084
256
4508.501
0.00667852
257
4494.129
0.16070330
258
4483.352
0.07541426
259
4477.786
0.00396937
260
4473.629
0.01359221
261
4469.021
0.00077004
262
4461.971
0.08205598
263
4461.245
0.01904471
264
2964.423
0.00816103
265
2960.784
0.32038319
266
2959.602
0.05155445
267
2952.285
0.01412862
268
4541.543
0.00018599
269
4537.791
0.04486604
270
4534.672
0.14826169
271
4528.574
0.00112494
272
4510.983
0.03487475
273
4506.095
0.01234373
274
4491.723
0.06056434
275
4480.946
0.17503730
276
4475.380
0.00130997
277
4471.223
0.02521703
278
4466.616
0.06622961
279
4459.565
0.00818024
280
4458.839
0.04443797
281
2962.017
0.00959049
282
2958.378
0.96540305
283
2957.196
0.06593004
284
2949.879
0.33799609
285
2908.102
0.87659921
286
4538.478
0.00018735
287
4534.726
0.17056228
288
4531.607
0.02044280
289
4525.509
0.00071221
290
4507.918
0.01071929
291
4503.030
0.00631453
292
4488.658
0.08082717
293
4477.881
0.00161606
294
4472.315
0.00491188
295
4468.158
0.11976203
296
4463.550
0.05944996
297
4456.500
0.01778292
298
4455.774
0.03594500
299
2958.952
0.01245324
300
2955.313
0.44240221
301
2954.131
0.11848928
302
2946.814
0.12056879
303
2905.037
1.26834515
304
2902.632
1.07832323
305
4506.118
0.28081321
306
4502.365
0.00105631
307
4499.246
0.00105595
308
4493.148
0.31071540
309
4475.557
0.00024779
310
4470.669
0.00037873
311
4456.298
0.14837011
312
4445.521
0.00099215
313
4439.954
0.37971248
314
4435.797
0.00326577
315
4431.190
0.00079395
316
4424.139
0.04730674
317
4423.413
0.03603295
318
2926.591
0.54443190
319
2922.953
0.02956075
320
2921.770
0.57429611
321
2914.453
0.00052844
322
2872.677
0.02808326
323
2870.271
0.00741301
324
2867.206
0.01453014
325
4439.616
0.00011930
326
4435.864
0.00560140
327
4432.745
0.00653713
328
4426.647
0.00016860
329
4409.056
0.02381604
330
4404.168
0.00184092
331
4389.796
0.00066921
332
4379.019
0.01045835
333
4373.453
0.00069947
334
4369.296
0.00226916
335
4364.689
0.08047749
336
4357.638
0.01565475
337
4356.912
0.01376419
338
2860.090
0.00111428
339
2856.451
0.12283756
340
2855.269
0.00505152
341
2847.952
0.15981049
342
2806.175
0.01833343
343
2803.770
0.00561784
344
2800.704
0.01762329
345
2768.344
0.00035838
346
4433.851
0.00022154
347
4430.099
0.01560645
348
4426.980
0.02432698
349
4420.881
0.00034247
350
4403.291
0.00619669
351
4398.403
0.00959939
352
4384.031
0.00523006
353
4373.254
0.03021786
354
4367.688
0.00129468
355
4363.531
0.04311281
356
4358.923
0.02393204
357
4351.873
0.03188230
358
4351.147
0.05233234
359
2854.325
0.00186341
360
2850.686
0.22093848
361
2849.503
0.00797003
362
2842.186
0.08611084
363
2800.410
0.00149768
364
2798.004
0.04519067
365
2794.939
0.01725762
366
2762.579
0.00049811
367
2696.077
0.38729437
368
4376.292
0.00328676
369
4372.540
0.00789617
370
4369.421
0.01500034
371
4363.322
0.00131604
372
4345.732
0.00188496
373
4340.844
0.01395426
374
4326.472
0.00071204
375
4315.695
0.01654870
376
4310.129
0.00269889
377
4305.972
0.01781163
378
4301.364
0.00968551
379
4294.314
0.03902426
380
4293.588
0.04849144
381
2796.766
0.00185589
382
2793.127
0.05383613
383
2791.944
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1371
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1408
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1412
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1421
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1422
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1423
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1424
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1425
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1426
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1427
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1428
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1429
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1430
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1431
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1432
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1433
956.691
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1434
908.790
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1435
846.109
14.03110531
1436
750.074
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1437
697.346
25.36633118
1438
571.195
0.01703089
1439
531.541
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1440
511.949
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1441
3293.855
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1442
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1443
3286.983
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1444
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1446
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1447
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1448
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1449
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1450
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1451
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1452
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1453
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1454
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1455
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1456
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1457
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1458
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1459
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1460
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1461
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1462
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1463
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1465
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1466
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1467
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1468
1430.636
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1469
1387.795
0.01420175
1470
1309.865
0.00572015
1471
1258.893
0.00905840
1472
1231.629
0.00403543
1473
1228.299
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1474
1186.118
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1475
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1476
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1477
1136.113
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1478
1069.211
0.04594315
1479
1055.985
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1480
1051.763
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1481
990.827
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1482
924.602
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1483
918.637
0.09440950
1484
907.048
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1485
859.148
0.46959206
1486
796.466
0.41498034
1487
700.431
5.65281922
1488
647.703
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1489
521.552
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1490
481.898
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1491
462.306
0.01002236
1492
459.962
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1493
3257.538
0.37410198
1494
3253.786
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1495
3250.667
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1496
3244.569
0.45531935
1497
3226.978
0.00798014
1498
3222.090
0.00336089
1499
3207.719
0.09654107
1500
3196.941
0.00290253
1501
3191.375
0.00323457
1502
3187.218
0.01054128
1503
3182.611
0.00536444
1504
3175.560
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1505
3174.834
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1506
1678.012
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1507
1674.373
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1508
1673.191
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1509
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1510
1624.098
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1511
1621.692
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1512
1618.627
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1513
1586.266
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1514
1519.765
0.00056566
1515
1513.999
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1516
1456.440
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1517
1452.649
0.04810575
1518
1445.023
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1519
1433.873
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1520
1394.320
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1521
1351.479
0.00363116
1522
1273.549
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1523
1222.577
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1524
1195.313
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1525
1191.983
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1526
1149.802
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1527
1142.411
0.07292785
1528
1122.828
0.32430351
1529
1099.797
0.19307580
1530
1032.894
0.11172879
1531
1019.668
0.31895607
1532
1015.447
0.02509278
1533
954.510
0.17184478
1534
888.286
0.18138369
1535
882.321
0.57271922
1536
870.732
0.66724129
1537
822.831
0.32893972
1538
760.150
0.58802318
1539
664.115
0.01934108
1540
611.387
0.03414085
1541
485.236
0.00270359
1542
445.582
0.00299127
1543
425.990
0.08659490
1544
423.646
0.00590081
1545
374.003
0.00035546
1546
3204.229
0.02740917
1547
3200.477
0.00542573
1548
3197.357
0.04641095
1549
3191.259
0.08761924
1550
3173.668
0.04812225
1551
3168.781
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1552
3154.409
0.06021976
1553
3143.632
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1554
3138.066
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1555
3133.908
0.03214376
1556
3129.301
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1557
3122.251
0.04414229
1558
3121.524
0.04806017
1559
1624.702
0.00490787
1560
1621.064
0.00057749
1561
1619.881
0.01512167
1562
1612.564
0.00351839
1563
1570.788
0.01544519
1564
1568.382
0.00463300
1565
1565.317
0.00357405
1566
1532.957
0.06031480
1567
1466.455
0.00551703
1568
1460.690
0.00339588
1569
1403.131
0.01164609
1570
1399.340
0.00729026
1571
1391.713
0.02310742
1572
1380.564
0.00627080
1573
1341.011
0.00242355
1574
1298.169
0.00795864
1575
1220.239
0.00942522
1576
1169.267
0.00953756
1577
1142.003
0.00621265
1578
1138.673
0.00147762
1579
1096.492
0.05803866
1580
1089.101
0.07627040
1581
1069.518
0.06589389
1582
1046.487
0.00425893
1583
979.585
0.00521525
1584
966.359
0.04287710
1585
962.138
0.00150962
1586
901.201
0.02752766
1587
834.976
0.96132084
1588
829.012
0.10570855
1589
817.423
0.12274053
1590
769.522
0.38561764
1591
706.840
2.03674861
1592
610.805
0.00977868
1593
558.077
0.03303057
1594
431.926
0.00811341
1595
392.272
0.01309889
1596
372.680
0.00007948
1597
370.336
0.00484853
1598
320.694
0.00045965
1599
284.377
0.00566592
1600
3163.693
0.12754478
1601
3159.941
0.03577794
1602
3156.822
0.04184734
1603
3150.724
0.18017007
1604
3133.133
0.01767941
1605
3128.245
0.09403302
1606
3113.873
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1607
3103.096
0.00618106
1608
3097.530
0.36910309
1609
3093.373
0.03342244
1610
3088.766
0.10636962
1611
3081.715
48.54537254
1612
3080.989
1.24905225
1613
1584.167
0.06772382
1614
1580.528
0.00212235
1615
1579.346
0.03703571
1616
1572.029
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1617
1530.252
0.01652444
1618
1527.847
0.01766490
1619
1524.781
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1620
1492.421
0.18865611
1621
1425.919
0.00239392
1622
1420.154
0.00129075
1623
1362.595
0.00066447
1624
1358.804
0.00115693
1625
1351.178
0.00397514
1626
1340.028
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1627
1300.475
0.03015058
1628
1257.633
0.02929294
1629
1179.704
0.63541471
1630
1128.732
0.04039236
1631
1101.468
1.77642023
1632
1098.138
0.00410784
1633
1055.957
0.11014136
1634
1048.566
0.01318188
1635
1028.983
0.05974348
1636
1005.952
0.01332009
1637
939.049
0.14501982
1638
925.823
0.00452105
1639
921.602
0.00628212
1640
860.665
0.41812070
1641
794.440
5.46216426
1642
788.476
4.04732446
1643
776.887
8.22176804
1644
728.986
0.18528675
1645
666.305
0.07585370
1646
570.270
0.02832708
1647
517.542
0.03414915
1648
391.390
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1649
351.736
0.07286788
1650
332.144
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1651
329.801
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1652
280.158
0.00115190
1653
243.842
0.00336434
1654
190.532
0.00418900
1655
3143.171
0.08828984
1656
3139.419
0.03762845
1657
3136.300
0.03684059
1658
3130.202
0.02525237
1659
3112.611
0.06052753
1660
3107.723
0.14350267
1661
3093.351
0.12082136
1662
3082.574
4.39604240
1663
3077.008
0.01140359
1664
3072.851
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1665
3068.243
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1666
3061.193
0.74175969
1667
3060.467
0.42457200
1668
1563.645
0.02214496
1669
1560.006
0.00188692
1670
1558.824
0.00801678
1671
1551.507
0.00293274
1672
1509.730
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1673
1507.324
0.00451710
1674
1504.259
0.10634075
1675
1471.899
0.04662041
1676
1405.397
0.00236370
1677
1399.632
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1678
1342.073
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1679
1338.282
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1680
1330.655
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1681
1319.506
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1682
1279.953
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1683
1237.111
0.01394053
1684
1159.182
0.03610452
1685
1108.210
0.02461523
1686
1080.946
0.00629246
1687
1077.616
0.01496542
1688
1035.435
0.02034116
1689
1028.044
4.77051908
1690
1008.461
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1691
985.429
0.01692678
1692
918.527
0.01277691
1693
905.301
0.00760031
1694
901.080
0.02439101
1695
840.143
0.14613656
1696
773.918
1.11073869
1697
767.954
0.01351306
1698
756.365
0.56074195
1699
708.464
8.06440168
1700
645.782
0.41661272
1701
549.748
0.00443306
1702
497.020
1.16236457
1703
370.868
0.02293506
1704
331.214
0.18909215
1705
311.622
0.00127144
1706
309.279
0.04703790
1707
259.636
0.00161095
1708
223.320
0.00154098
1709
170.010
0.00118097
1710
129.474
0.00065364
IR Spectrum
Raman Spectrum
Peak Width (cm
-1
)
Quote
CHINESE FORTUNE COOKIE OF JAN 1 1967 SAY.... ALL THINGS ARE DIFFICULT BEFORE THEY ARE EASY. WE LEARN SO LITTLE AND FORGET SO MUCH. YOU WILL OVERCOME OBSTACLES TO ACHIEVE SUCCESS. AH SO.