WebMO Job Summary
392: C6H13FSi 1-ETHYL-1-FLUOROSILACYCLOPENTANE conformer B C1 30Si, Opt + Ultrafine Anharmonic Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT(maxstep=10,maxcycles=50,VeryTight) FREQ(Anharmonic,vibrot) int=ultrafine
Method
B3LYP
Stoichiometry
C
6
H
13
FSi
Symmetry
C1
Basis
6-311+G(2d,p)
RB3LYP Energy
-626.034793616 Hartree
ZPE
0.179972 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-625.844924 Hartree
Enthalpy
-625.843980 Hartree
Free Energy
-625.890197 Hartree
C
v
36.811 cal/mol-K
Entropy
97.272 cal/mol-K
Dipole Moment
1.8859 Debye
Server
batch (119428)
CPU time
627447.5 sec
Geometry Sequence Energies
Step
Energy (au)
0
-626.034857418
1
-626.034857418
2
-626.034857418
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
2.70534
0.09024042893
b
1.10930
0.03700226508
c
1.08092
0.03605561018
Partial Charges
Atom
Symbol
Charge
1
C
-0.718038
2
Si
1.662840
3
C
-0.680559
4
C
-0.183792
5
C
-0.131485
6
H
0.100095
7
H
0.111654
8
H
0.105078
9
H
0.100213
10
H
0.131972
11
H
0.114431
12
F
-0.530442
13
C
-0.451470
14
C
-0.497162
15
H
0.139257
16
H
0.116737
17
H
0.121671
18
H
0.124018
19
H
0.120655
20
H
0.121408
21
H
0.122919
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
54.3923
0.0638
2
A
74.9471
0.6943
3
A
115.4236
0.3993
4
A
168.7659
1.4883
5
A
205.0360
3.1895
6
A
254.3780
5.1354
7
A
257.0366
0.5362
8
A
276.5485
2.5601
9
A
315.4768
7.0366
10
A
440.5538
20.1453
11
A
494.8636
2.1922
12
A
591.0896
3.7169
13
A
652.3918
10.4289
14
A
698.2976
66.5622
15
A
711.8034
30.1488
16
A
718.5068
6.3427
17
A
782.1968
84.1370
18
A
842.6287
105.9671
19
A
850.4972
3.9742
20
A
863.3249
14.6899
21
A
930.9226
1.1574
22
A
953.9021
1.2008
23
A
973.2738
3.0927
24
A
980.5911
5.7104
25
A
1023.1064
4.7775
26
A
1026.3274
34.1490
27
A
1053.1387
10.7961
28
A
1104.5087
46.8690
29
A
1182.6224
3.5555
30
A
1225.4717
0.3759
31
A
1264.9854
1.4009
32
A
1276.0637
4.6313
33
A
1283.7116
7.5112
34
A
1287.5438
0.8553
35
A
1345.1161
1.5558
36
A
1350.9173
1.0738
37
A
1417.4171
1.1767
38
A
1449.7795
8.3102
39
A
1452.8450
3.5734
40
A
1455.2514
9.4743
41
A
1497.0291
5.2143
42
A
1504.3449
5.2870
43
A
1505.5280
1.8869
44
A
1509.1664
5.9198
45
A
3005.9901
6.2294
46
A
3006.7166
30.6474
47
A
3013.7670
22.4705
48
A
3018.3742
24.0852
49
A
3022.5315
40.0461
50
A
3028.0973
13.9882
51
A
3038.8742
7.4239
52
A
3053.2463
47.5647
53
A
3058.1345
48.4944
54
A
3075.7252
32.5334
55
A
3081.8230
18.4588
56
A
3084.9420
19.0816
57
A
3088.6948
28.3661
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Anharmonic Vibrational Modes
Mode
Frequency (cm
-1
)
IR Intensity
Raman Intensity
1
2965.870
34.52176444
2
2951.136
38.49467514
3
2958.100
37.31698834
4
2943.448
35.27393475
5
2912.974
43.41741287
6
2921.533
27.88724249
7
2894.171
5.28804460
8
2902.467
13.38102579
9
2868.584
32.34339974
10
2894.478
25.62956660
11
2827.616
32.18280726
12
2869.912
8.74840523
13
2863.964
7.27548255
14
1466.802
6.36571989
15
1476.442
2.32209185
16
1455.292
3.30637186
17
1459.298
2.83440742
18
1422.269
0.84221847
19
1419.600
3.63328371
20
1414.679
6.03822116
21
1386.224
0.93434771
22
1318.187
0.94460079
23
1314.955
1.39908612
24
1257.142
0.55785654
25
1252.868
3.76917990
26
1243.020
3.36715760
27
1233.761
1.31283471
28
1198.821
0.44167597
29
1154.007
2.85338929
30
1084.069
18.72992299
31
1035.994
9.43054280
32
1002.647
15.63663609
33
995.638
10.63878135
34
965.354
4.98651196
35
959.521
1.37503697
36
939.370
0.42681559
37
916.257
0.79649736
38
845.772
18.62343179
39
832.579
4.06352214
40
827.882
95.29642379
41
770.112
69.82807070
42
709.186
6.06569222
43
702.308
22.37743913
44
682.207
32.54226244
45
643.142
9.32540978
46
584.005
3.19387724
47
492.986
2.16965042
48
435.533
19.48007600
49
311.990
6.86152716
50
269.668
1.27988133
51
283.404
6.41766684
52
248.906
3.44361765
53
207.018
2.94554558
54
154.706
0.68680746
55
114.292
0.17510084
56
67.561
0.16961442
57
46.316
0.15696445
58
5853.479
0.26269194
59
5802.875
0.47542649
60
5807.321
0.43920196
61
5810.187
0.51086914
62
5843.657
0.01284555
63
5785.950
0.46955425
64
5668.519
0.31865826
65
5738.023
0.41720317
66
5729.313
0.00808023
67
5746.117
0.15565669
68
5700.648
0.50027094
69
5767.463
0.05278578
70
5758.747
0.07472481
71
2950.329
4.70384080
72
2940.220
2.26420572
73
2935.805
6.87592281
74
2923.415
41.29663112
75
2841.192
0.21013903
76
2826.891
1.41085411
77
2816.672
0.61439962
78
2743.881
2.04584036
79
2629.974
0.07991369
80
2616.774
0.27916212
81
2510.969
0.01094230
82
2501.315
0.03154945
83
2477.416
0.00230167
84
2461.225
0.03948789
85
2395.372
0.05578580
86
2303.948
0.00881314
87
2164.574
0.06443836
88
2071.475
0.03869460
89
1993.983
0.01000989
90
1986.890
0.00260531
91
1931.075
0.06586987
92
1912.868
0.06298436
93
1872.036
0.00005667
94
1832.701
0.00938565
95
1689.776
0.03826170
96
1662.891
0.00252897
97
1653.787
0.10611294
98
1537.928
0.20316203
99
1406.341
0.64972464
100
1401.627
0.33039016
101
1369.468
0.12827569
102
1285.360
0.32522792
103
1165.639
0.13316491
104
985.920
0.05884035
105
870.678
0.18865206
106
623.426
0.10678584
107
537.459
0.00603016
108
499.624
0.07463621
109
499.758
0.00234288
110
408.874
0.01139078
111
347.016
0.01175003
112
231.192
0.01032539
113
151.188
0.00201458
114
99.382
0.00156807
115
6173.637
0.00084955
116
6170.518
0.00198589
117
6166.765
0.02907702
118
6164.420
0.23925145
119
6160.667
0.00115346
120
6157.548
0.00355958
121
6146.829
0.00031868
122
6143.077
0.03213305
123
6139.957
0.06021702
124
6133.860
0.00040941
125
6141.941
0.00018522
126
6138.188
0.00478096
127
6135.069
0.00922637
128
6128.972
0.00009998
129
6111.381
0.29522316
130
6127.569
0.09086478
131
6123.816
0.00008232
132
6120.697
0.00033064
133
6114.599
0.05604366
134
6097.009
0.00172008
135
6092.121
0.00175876
136
6116.792
0.00000171
137
6113.039
0.00068901
138
6109.920
0.23072151
139
6103.823
0.00030377
140
6086.232
0.09003237
141
6081.344
0.08666754
142
6066.972
0.00036354
143
6111.226
0.03795306
144
6107.473
0.00170878
145
6104.354
0.00071843
146
6098.257
0.17767434
147
6080.666
0.00151554
148
6075.778
0.00071191
149
6061.406
0.03541990
150
6050.629
0.00111115
151
6107.069
0.00018642
152
6103.316
0.13880235
153
6100.197
0.00672953
154
6094.099
0.00115903
155
6076.509
0.15060272
156
6071.621
0.10213484
157
6057.248
0.01152833
158
6046.471
0.00352690
159
6040.906
0.00015066
160
6102.462
0.00010479
161
6098.709
0.04451858
162
6095.590
0.01342630
163
6089.492
0.00028107
164
6071.902
0.10408793
165
6067.013
0.27241628
166
6052.641
0.00045961
167
6041.864
0.02358465
168
6036.299
0.00025862
169
6032.141
0.17413252
170
6095.411
0.00568001
171
6091.659
0.00398574
172
6088.540
0.02851438
173
6082.442
0.02484823
174
6064.851
0.12222940
175
6059.963
0.03999827
176
6045.591
0.24232130
177
6034.814
0.00400108
178
6029.248
0.02458407
179
6025.091
0.00318175
180
6020.484
0.07321344
181
6094.685
0.00386200
182
6090.932
0.00877661
183
6087.813
0.01285609
184
6081.715
0.01418444
185
6064.125
0.14608862
186
6059.236
0.05622089
187
6044.864
0.21341991
188
6034.087
0.00120155
189
6028.522
0.01789318
190
6024.364
0.02584646
191
6019.757
0.08097013
192
6012.707
0.02651751
193
4597.861
0.18264051
194
4594.108
0.00108720
195
4590.989
0.00015297
196
4584.892
0.14898430
197
4567.301
0.00110388
198
4562.413
0.00126153
199
4548.041
0.03108431
200
4537.264
0.00028180
201
4531.698
0.17118736
202
4527.541
0.00160558
203
4522.933
0.00050971
204
4515.883
0.00309299
205
4515.157
0.00452368
206
4594.223
0.00774723
207
4590.470
0.01314252
208
4587.351
0.01245282
209
4581.253
0.01709481
210
4563.663
0.14068962
211
4558.774
0.18122941
212
4544.402
0.00294709
213
4533.625
0.01957625
214
4528.059
0.01205058
215
4523.902
0.05382274
216
4519.295
0.13231662
217
4512.245
0.00864009
218
4511.518
0.01719370
219
3014.694
10.31953138
220
4593.040
0.15112055
221
4589.287
0.00198597
222
4586.168
0.00156928
223
4580.070
0.26289606
224
4562.479
0.00829948
225
4557.591
0.00831422
226
4543.219
0.03133052
227
4532.442
0.00177040
228
4526.876
0.18121897
229
4522.719
0.00131883
230
4518.112
0.00539642
231
4511.062
0.00772310
232
4510.335
0.00173046
233
3013.511
4.83961043
234
3009.873
11.08445419
235
4585.724
0.00020730
236
4581.971
0.00392649
237
4578.852
0.00545716
238
4572.754
0.00035875
239
4555.164
0.12504668
240
4550.275
0.21012231
241
4535.903
0.00073319
242
4525.126
0.04342759
243
4519.561
0.00026691
244
4515.403
0.09770118
245
4510.796
0.23249664
246
4503.746
0.15483253
247
4503.019
0.20679028
248
3006.195
51.93054027
249
3002.557
9.54965835
250
3001.374
7.97349009
251
4543.946
0.00046800
252
4540.193
0.04610628
253
4537.074
0.09053880
254
4530.977
0.00249109
255
4513.386
0.00102866
256
4508.498
0.00668666
257
4494.126
0.16065019
258
4483.349
0.07548206
259
4477.783
0.00396596
260
4473.626
0.01363999
261
4469.018
0.00077602
262
4461.968
0.08203039
263
4461.242
0.01906634
264
2964.418
0.00812559
265
2960.779
0.31996887
266
2959.596
0.05167404
267
2952.281
0.01412086
268
4541.540
0.00018622
269
4537.787
0.04488165
270
4534.668
0.14832222
271
4528.570
0.00112362
272
4510.979
0.03486733
273
4506.091
0.01233028
274
4491.719
0.06052901
275
4480.942
0.17515968
276
4475.376
0.00131024
277
4471.219
0.02523858
278
4466.612
0.06620898
279
4459.562
0.00818345
280
4458.835
0.04443536
281
2962.011
0.00952847
282
2958.373
0.96462515
283
2957.190
0.06556596
284
2949.874
0.33777504
285
2908.096
0.87636653
286
4538.474
0.00018759
287
4534.721
0.17054771
288
4531.602
0.02036829
289
4525.505
0.00071184
290
4507.914
0.01071693
291
4503.026
0.00630678
292
4488.654
0.08091969
293
4477.877
0.00160719
294
4472.311
0.00491390
295
4468.154
0.11977866
296
4463.547
0.05945423
297
4456.496
0.01780476
298
4455.770
0.03600730
299
2958.946
0.01238334
300
2955.307
0.44194378
301
2954.124
0.11809556
302
2946.809
0.12050158
303
2905.031
1.26834419
304
2902.624
1.07684803
305
4506.112
0.28090104
306
4502.359
0.00105619
307
4499.240
0.00105099
308
4493.142
0.31080557
309
4475.552
0.00024770
310
4470.663
0.00037763
311
4456.291
0.14837222
312
4445.514
0.00098107
313
4439.949
0.37987288
314
4435.791
0.00327520
315
4431.184
0.00079652
316
4424.134
0.04728167
317
4423.407
0.03603475
318
2926.583
0.54438850
319
2922.945
0.02933828
320
2921.762
0.57431914
321
2914.446
0.00052767
322
2872.669
0.02817467
323
2870.262
0.00747532
324
2867.197
0.01455285
325
4439.612
0.00011865
326
4435.859
0.00560626
327
4432.740
0.00653574
328
4426.643
0.00017040
329
4409.052
0.02382624
330
4404.164
0.00184303
331
4389.792
0.00067357
332
4379.015
0.01042419
333
4373.449
0.00070175
334
4369.291
0.00227785
335
4364.684
0.08048350
336
4357.634
0.01565013
337
4356.907
0.01377735
338
2860.084
0.00111176
339
2856.445
0.12272602
340
2855.262
0.00501140
341
2847.946
0.15970457
342
2806.169
0.01831542
343
2803.762
0.00563408
344
2800.697
0.01760603
345
2768.334
0.00036174
346
4433.811
0.00021705
347
4430.058
0.01557022
348
4426.939
0.02429559
349
4420.841
0.00033889
350
4403.251
0.00623970
351
4398.362
0.00958843
352
4383.990
0.00517435
353
4373.213
0.03023309
354
4367.648
0.00127342
355
4363.490
0.04311353
356
4358.883
0.02397573
357
4351.833
0.03193801
358
4351.106
0.05224788
359
2854.282
0.00186306
360
2850.644
0.22083645
361
2849.461
0.00792781
362
2842.145
0.08621075
363
2800.368
0.00147933
364
2797.961
0.04515219
365
2794.896
0.01722371
366
2762.533
0.00048046
367
2696.033
0.38734811
368
4376.239
0.00327813
369
4372.486
0.00787754
370
4369.367
0.01504589
371
4363.269
0.00137978
372
4345.678
0.00186841
373
4340.790
0.01397788
374
4326.418
0.00071725
375
4315.641
0.01665904
376
4310.075
0.00272895
377
4305.918
0.01791285
378
4301.311
0.00964396
379
4294.260
0.03898741
380
4293.534
0.04842127
381
2796.710
0.00186063
382
2793.072
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1439
530.927
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1450
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1451
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1452
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1453
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1471
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1481
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1483
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1484
903.334
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1485
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1486
796.126
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1487
699.900
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1488
645.590
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1489
520.513
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1490
481.584
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1491
462.073
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1492
459.414
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1493
3257.461
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1494
3253.708
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1495
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1496
3244.491
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1497
3226.900
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1498
3222.012
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1499
3207.640
0.09813947
1500
3196.863
0.00294873
1501
3191.297
0.00325756
1502
3187.140
0.01057980
1503
3182.533
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1504
3175.483
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1505
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1506
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1507
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1508
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1509
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1510
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1511
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1512
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1513
1586.183
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1514
1519.683
0.00057431
1515
1513.882
0.00381359
1516
1456.310
0.67723193
1517
1452.477
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1518
1444.830
0.24175977
1519
1433.751
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1520
1394.238
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1521
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1522
1273.275
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1523
1221.905
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1524
1195.093
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1525
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1526
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1527
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1528
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1529
1099.688
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1530
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1531
1019.263
0.23798120
1532
1011.395
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1533
950.963
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1534
887.273
0.09810734
1535
880.569
0.54349970
1536
867.063
1.12816671
1537
821.158
0.31865080
1538
759.855
0.72330142
1539
663.630
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1540
609.320
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1541
484.243
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1542
445.314
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1543
425.802
0.11204192
1544
423.144
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1545
373.802
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1546
3204.118
0.02772903
1547
3200.366
0.00535145
1548
3197.247
0.04651140
1549
3191.149
0.08743421
1550
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0.04810503
1551
3168.670
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1552
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0.06034602
1553
3143.521
0.00218729
1554
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1555
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1556
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0.01137486
1557
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0.04423186
1558
3121.414
0.04795804
1559
1624.590
0.00494380
1560
1620.952
0.00051328
1561
1619.769
0.01497197
1562
1612.453
0.00358895
1563
1570.675
0.01615417
1564
1568.269
0.00488155
1565
1565.203
0.00344841
1566
1532.841
0.05986653
1567
1466.341
0.00547470
1568
1460.540
0.00296417
1569
1402.967
0.01186921
1570
1399.135
0.00975007
1571
1391.487
0.02280574
1572
1380.409
0.00644081
1573
1340.895
0.00246613
1574
1298.046
0.00797439
1575
1219.932
0.01127838
1576
1168.562
0.00820054
1577
1141.751
0.00616425
1578
1138.530
0.00154829
1579
1096.015
0.05661211
1580
1088.697
0.07248716
1581
1069.326
0.06427235
1582
1046.346
0.00448280
1583
978.748
0.00650941
1584
965.921
0.03643856
1585
958.052
0.00411758
1586
897.620
0.02205637
1587
833.930
1.79798837
1588
827.227
0.08183006
1589
813.721
0.10669202
1590
767.815
0.46543036
1591
706.513
11.88137665
1592
610.287
0.01478825
1593
555.977
0.03012216
1594
430.900
0.00884988
1595
391.972
0.01504818
1596
372.460
0.00009097
1597
369.802
0.00554972
1598
320.460
0.00032852
1599
284.189
0.00586906
1600
3163.642
0.12763732
1601
3159.889
0.03565398
1602
3156.770
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1603
3150.672
0.18034234
1604
3133.082
0.01742565
1605
3128.193
0.09259487
1606
3113.821
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1607
3103.044
0.00612142
1608
3097.479
0.37246307
1609
3093.321
0.03470210
1610
3088.714
0.10711236
1611
3081.664
22.57930820
1612
3080.937
1.12407407
1613
1584.113
0.06772321
1614
1580.475
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1615
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1616
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1617
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1618
1527.792
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1619
1524.727
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1620
1492.364
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1621
1425.864
0.00243012
1622
1420.063
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1623
1362.491
0.00058108
1624
1358.659
0.00122228
1625
1351.011
0.00403523
1626
1339.932
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1627
1300.419
0.02931010
1628
1257.569
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1629
1179.456
0.54280173
1630
1128.086
0.04262367
1631
1101.274
1.71720014
1632
1098.053
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1633
1055.538
0.10612483
1634
1048.221
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1635
1028.849
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1636
1005.870
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1637
938.272
0.17536277
1638
925.444
0.00339211
1639
917.576
0.01135392
1640
857.144
0.69904087
1641
793.454
4.37259315
1642
786.750
0.36887544
1643
773.245
6.90867502
1644
727.339
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1645
666.037
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1646
569.811
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1647
515.501
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1648
390.424
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1649
351.496
0.07272655
1650
331.984
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1651
329.325
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1652
279.983
0.00101853
1653
243.713
0.00332396
1654
190.371
0.00395354
1655
3143.087
0.08801223
1656
3139.334
0.03759428
1657
3136.215
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1658
3130.118
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1659
3112.527
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1660
3107.639
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1661
3093.267
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1662
3082.490
5.68675580
1663
3076.924
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1664
3072.766
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1665
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1666
3061.109
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1667
3060.382
0.47116981
1668
1563.559
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1669
1559.920
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1670
1558.737
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1671
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1672
1509.644
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1673
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1674
1504.172
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1675
1471.809
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1676
1405.310
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1677
1399.508
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1678
1341.936
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1679
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1680
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1681
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1682
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1683
1237.015
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1684
1158.901
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1685
1107.531
0.02398028
1686
1080.720
0.00638532
1687
1077.499
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1688
1034.983
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1689
1027.666
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1690
1008.294
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1691
985.315
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1692
917.717
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1693
904.889
0.00651705
1694
897.021
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1695
836.589
1.43562949
1696
772.899
2.14305058
1697
766.196
0.03495157
1698
752.690
0.37537261
1699
706.784
6.11937563
1700
645.482
0.66767821
1701
549.256
0.00312379
1702
494.946
0.20506112
1703
369.869
0.02387511
1704
330.941
0.16717776
1705
311.429
0.00131308
1706
308.770
0.04535287
1707
259.428
0.00114157
1708
223.158
0.00254603
1709
169.816
0.00130638
1710
129.339
0.00080369
IR Spectrum
Raman Spectrum
Peak Width (cm
-1
)
Quote
BLACK HOLES SUCK.