WebMO Job Summary

485828: dimethyl ether C2H6O, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C2H6O
Symmetry C2V
Basis 6-31G(d)
RB3LYP Energy -155.025051461 Hartree
ZPE 0.080324 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -154.940442 Hartree
Enthalpy -154.939498 Hartree
Free Energy -154.969429 Hartree
Cv 12.828 cal/mol-K
Entropy 62.993 cal/mol-K
Dipole Moment 1.2738 Debye
Server batch (498859)
CPU time 61.7 sec

Geometry Sequence Energies

Step Energy  
0 -155.016014807  
1 -155.023681590  
2 -155.025009483  
3 -155.025050952  
4 -155.025051461  
5 -155.025051461  
6 -155.025051461  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 39.16409 1.30637342451
b 10.01204 0.33396570637
c 8.87362 0.29599210264

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A2 224.6314 0.0000
2 B1 253.9430 6.3331
3 A1 416.0111 2.6017
4 A1 958.4130 34.7403
5 B2 1136.9680 37.3858
6 A2 1175.2733 0.0000
7 B1 1210.0320 6.5236
8 B2 1216.1856 108.1329
9 A1 1279.7581 4.8165
10 B2 1484.7045 10.9902
11 A2 1509.8609 0.0000
12 A1 1517.9872 0.0582
13 B1 1519.1000 9.2004
14 B2 1527.8426 13.5506
15 A1 1549.5624 0.3217
16 B2 2974.3370 57.1413
17 A1 2989.4485 63.1168
18 B1 3021.2686 160.5274
19 A2 3024.5115 0.0000
20 B2 3133.2374 36.9110
21 A1 3134.8879 30.0507
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

NOT WHAT WE DID SHALL BE THE TEST WHEN ACT AND WILL ARE DONE, BUT WHAT OUR LORD INFERS WE WOULD- HAD WE DIVINER BEEN. EMILY DICKINSON POEMS NO. CLXXV