WebMO Job Summary

508360: C2H4O2 ozonolysis of trans 2-butene zwitterion intermediate, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C2H4O2
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -228.903365128 Hartree
ZPE 0.059241 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -228.840011 Hartree
Enthalpy -228.839067 Hartree
Free Energy -228.870275 Hartree
Cv 12.830 cal/mol-K
Entropy 65.684 cal/mol-K
Dipole Moment 4.8336 Debye
Server batch (521403)
CPU time 240.6 sec

Geometry Sequence Energies

Step Energy  
0 -228.896357042  
1 -228.902140575  
2 -228.903251038  
3 -228.903359612  
4 -228.903365128  
5 -228.903365128  
6 -228.903365128  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 49.19674 1.64102660648
b 4.39652 0.14665212158
c 4.13992 0.13809286690

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" -176.3761 2.3900
2 A" 252.8040 0.7900
3 A' 326.3586 7.5470
4 A' 560.9827 4.7092
5 A" 842.2072 17.1982
6 A' 918.2480 41.4236
7 A' 1035.9421 63.5346
8 A" 1063.2581 0.0410
9 A' 1159.1688 11.6088
10 A' 1352.7147 21.9438
11 A' 1440.7741 12.0147
12 A' 1499.2480 5.1384
13 A" 1500.1743 8.6272
14 A' 1560.0708 4.4827
15 A' 3047.9889 5.2573
16 A" 3099.0879 4.5192
17 A' 3155.3022 6.4510
18 A' 3189.5316 7.3731
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

MARY HAD A LITTLE LAMB HIS FEET WERE BLACK AS SOOT, AND EVERYWHERE THAT MARY WENT HIS SOOTY FOOT HE PUT. -- NONAME