WebMO Job Summary

509365: C7H13(+1) 1-methylcyclohexene tertiary cation, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C7H13(1+)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -274.302334639 Hartree
ZPE 0.186048 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -274.108917 Hartree
Enthalpy -274.107973 Hartree
Free Energy -274.147326 Hartree
Cv 28.583 cal/mol-K
Entropy 82.825 cal/mol-K
Dipole Moment 1.8650 Debye
Server batch (522405)
CPU time 1160.2 sec

Geometry Sequence Energies

Step Energy  
0 -274.280960011  
1 -274.296672143  
2 -274.298518507  
3 -274.298811442  
4 -274.299555544  
5 -274.300728507  
6 -274.302147081  
7 -274.301826825  
8 -274.302288254  
9 -274.302334210  
10 -274.302334639  
11 -274.302334639  
12 -274.302334639  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 3.77158 0.12580636702
b 2.48459 0.08287700153
c 1.83738 0.06128839972

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A' 117.2802 3.2360
2 A" 142.5303 0.0454
3 A" 174.6588 2.7068
4 A' 299.0148 1.7700
5 A" 368.3774 10.5101
6 A" 417.2840 0.7977
7 A' 436.2503 1.2950
8 A' 510.1385 1.3692
9 A' 583.5977 11.4511
10 A" 738.6491 37.7998
11 A' 784.1448 12.9600
12 A' 805.1256 8.5859
13 A" 827.2635 1.9104
14 A' 858.0232 0.4222
15 A' 922.8590 35.3217
16 A" 961.8385 0.8616
17 A' 968.8228 22.4288
18 A" 999.4954 14.4977
19 A' 1024.8314 56.9572
20 A' 1045.7791 37.4480
21 A" 1046.2673 19.2688
22 A" 1100.4281 1.5806
23 A" 1104.4847 25.4239
24 A' 1185.1478 5.3617
25 A' 1232.0250 52.3287
26 A" 1251.6789 0.8105
27 A" 1270.6059 21.2072
28 A' 1300.4688 30.2648
29 A" 1317.5003 8.1321
30 A' 1343.0230 16.9234
31 A' 1382.0596 55.4385
32 A" 1389.2454 11.3650
33 A" 1403.4988 3.7560
34 A' 1422.4703 47.2387
35 A" 1456.7274 4.0498
36 A' 1502.7483 11.6301
37 A" 1508.4914 2.7962
38 A' 1513.6053 15.6686
39 A' 1527.1467 10.4643
40 A" 1531.3994 16.8692
41 A' 1551.6483 11.4469
42 A' 2976.0323 64.9852
43 A' 3060.9594 2.8156
44 A' 3078.6942 6.5085
45 A" 3080.5865 2.9132
46 A" 3084.2459 1.4667
47 A' 3092.3553 0.2974
48 A' 3100.6015 1.4859
49 A' 3103.5867 9.5984
50 A" 3136.2375 0.1857
51 A' 3137.7950 7.1068
52 A" 3159.2713 1.5761
53 A' 3162.2799 0.9405
54 A" 3166.1804 0.0558
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THE THINKER DIES, BUT HIS THOUGHTS ARE BEYOND THE REACH OF DESTRUCTION. MEN ARE MORTAL; BUT IDEAS ARE IMMORTAL. -- WALTER LIPPMANN