WebMO Job Summary

509366: C7H13(+1) 1-methylcyclohexene secondary cation, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C7H13(1+)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -274.283126855 Hartree
ZPE 0.185926 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -274.089639 Hartree
Enthalpy -274.088695 Hartree
Free Energy -274.128298 Hartree
Cv 29.215 cal/mol-K
Entropy 83.354 cal/mol-K
Dipole Moment 0.8219 Debye
Server batch (522406)
CPU time 2804.3 sec

Geometry Sequence Energies

Step Energy  
0 -274.258149388  
1 -274.272709167  
2 -274.274315334  
3 -274.273080609  
4 -274.275283462  
5 -274.276060940  
6 -274.272426548  
7 -274.280844735  
8 -274.281710848  
9 -274.282608644  
10 -274.282662499  
11 -274.282865655  
12 -274.282966978  
13 -274.283029114  
14 -274.283083719  
15 -274.283112179  
16 -274.283126049  
17 -274.283126661  
18 -274.283126855  
19 -274.283126855  
20 -274.283126855  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.66308 0.15554360610
b 2.09724 0.06995639630
c 1.60983 0.05369814874

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 110.1374 20.1684
2 A 197.3447 2.0517
3 A 204.8477 38.6276
4 A 275.0360 0.3933
5 A 296.8464 0.7003
6 A 326.4921 0.4338
7 A 425.8900 0.8165
8 A 481.6296 0.9880
9 A 533.7119 5.9464
10 A 588.7893 41.7222
11 A 758.6015 38.1798
12 A 812.8543 5.8613
13 A 869.3028 10.2964
14 A 900.4679 2.5397
15 A 915.1350 30.7956
16 A 945.8036 8.9576
17 A 999.7756 0.7401
18 A 1008.4312 57.3933
19 A 1022.3652 5.4933
20 A 1059.7696 3.6144
21 A 1069.0584 1.3410
22 A 1114.8141 4.9796
23 A 1150.9242 4.8317
24 A 1184.2468 0.9597
25 A 1227.5648 4.7346
26 A 1239.2714 17.3331
27 A 1243.9755 8.5576
28 A 1287.2199 2.7435
29 A 1295.0458 21.1036
30 A 1310.9326 2.4069
31 A 1355.8348 2.1725
32 A 1370.6678 0.1341
33 A 1398.1453 0.5286
34 A 1451.4835 4.6738
35 A 1491.5414 5.5194
36 A 1499.1027 14.1771
37 A 1507.3322 1.7079
38 A 1518.3301 2.8913
39 A 1524.1654 23.5778
40 A 1534.7622 9.8475
41 A 1567.7798 24.1921
42 A 3062.2850 2.2063
43 A 3071.0639 2.3321
44 A 3083.8374 2.6040
45 A 3088.4366 5.1987
46 A 3092.4451 1.3425
47 A 3105.8035 9.2844
48 A 3122.5404 2.0023
49 A 3140.8644 5.2902
50 A 3145.9558 1.1281
51 A 3147.0535 6.1686
52 A 3152.8234 1.8955
53 A 3154.7453 1.3380
54 A 3168.7259 0.7015
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

NOTHING WILL BE ATTEMPTED IF ALL POSSIBLE OBJECTIONS MUST FIRST BE OVERCOME. -- THE GOLDEN PRINCIPLE, PAUL DICKSON'S "THE OFFICIAL RULES"