WebMO Job Summary
513488: C6H13O(+1) protonated pinacolone syn, Optimize + Vib Freq - Gaussian
Raw Output
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry
C
6
H
13
O(1+)
Symmetry
CS
Basis
6-31G(d)
RB3LYP Energy
-311.510233751 Hartree
ZPE
0.182232 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-311.319546 Hartree
Enthalpy
-311.318602 Hartree
Free Energy
-311.360303 Hartree
C
v
31.659 cal/mol-K
Entropy
87.768 cal/mol-K
Dipole Moment
5.0903 Debye
Server
batch (526528)
CPU time
1039.1 sec
Geometry Sequence Energies
Step
Energy
0
-311.510233751
1
-311.510233751
2
-311.510233751
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
3.11464
0.10389320735
b
2.26640
0.07559896654
c
1.87629
0.06258629762
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A"
-107.8292
1.6152
2
A"
54.4684
3.8174
3
A"
173.0837
3.5356
4
A'
247.3303
0.6467
5
A"
251.3747
1.9658
6
A'
275.8293
1.4342
7
A"
289.8852
0.3868
8
A'
340.3640
1.0676
9
A"
359.4644
1.0181
10
A'
376.0330
1.5011
11
A'
472.4486
1.8196
12
A'
541.1233
12.4458
13
A"
608.4880
4.0323
14
A'
687.6443
11.0309
15
A"
736.8222
166.0253
16
A'
847.6989
27.5607
17
A"
938.2753
0.0224
18
A'
952.2483
6.8669
19
A'
979.3766
26.1457
20
A"
989.4211
0.0041
21
A"
1017.9954
21.4600
22
A'
1075.3131
2.9780
23
A"
1079.3512
16.8027
24
A'
1130.6265
137.2699
25
A"
1210.7813
0.3766
26
A'
1237.9698
4.7612
27
A'
1261.7922
69.3785
28
A'
1386.2017
22.6733
29
A"
1419.9563
0.4988
30
A'
1424.9490
118.0294
31
A'
1442.2474
43.6799
32
A"
1462.1467
29.7911
33
A'
1463.4908
126.5613
34
A'
1478.3292
114.5573
35
A"
1502.6292
0.0540
36
A"
1506.8318
0.0945
37
A'
1507.5778
0.6184
38
A'
1520.9674
14.2695
39
A"
1523.8818
15.2006
40
A'
1539.2703
42.2464
41
A'
1582.8604
149.9193
42
A'
3068.4336
25.6252
43
A"
3068.7485
21.9917
44
A'
3073.0661
5.5072
45
A'
3075.0849
12.7278
46
A"
3134.4426
4.2687
47
A"
3144.1140
10.3457
48
A'
3146.0898
0.0326
49
A"
3146.8864
27.7916
50
A'
3150.6326
31.1229
51
A"
3152.3193
6.4236
52
A'
3155.6932
41.9608
53
A'
3176.9208
3.1285
54
A'
3601.8053
246.4038
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
WE ARE PERHAPS NOT FAR REMOVED FROM THE TIME WHEN WE SHALL BE ABLE TO SUBMIT THE BULK OF CHEMICAL PHENOMENA TO CALCULATION. -- JOSEPH LOUIS GAY-LUSSAC MEMOIRES DE LA SOCIETE D'ARCUEIL, 2, 207 (1808)