WebMO Job Summary
513543: C5H9NBr(-1) 1-bromobutane and cyanide TS in acetonitrile, Transition State Optimization & - Gaussian
Raw Output
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT=(TS,NoEigenTest,NewEstmFC) SCRF=(PCM,Solvent=Ace
Stoichiometry
C
5
H
9
BrN(1-)
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-2822.48820172 Hartree
ZPE
0.129216 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-2822.349240 Hartree
Enthalpy
-2822.348295 Hartree
Free Energy
-2822.396451 Hartree
C
v
30.939 cal/mol-K
Entropy
101.353 cal/mol-K
Dipole Moment
8.9321 Debye
Server
batch (526583)
CPU time
4345.8 sec
Geometry Sequence Energies
Step
Energy
0
-2822.48832658
1
-2822.48869354
2
-2822.48772609
3
-2822.48795000
4
-2822.48797540
5
-2822.48810356
6
-2822.48819216
7
-2822.48819597
8
-2822.48819698
9
-2822.48819862
10
-2822.48819998
11
-2822.48820119
12
-2822.48820124
13
-2822.48820094
14
-2822.48820113
15
-2822.48820172
16
-2822.48820172
17
-2822.48820172
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.54300
0.05146893989
b
0.78544
0.02619945829
c
0.53943
0.01799344799
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
-421.9128
1373.6576
2
A
45.4814
5.9440
3
A
66.0988
7.2319
4
A
81.9444
7.9352
5
A
102.1871
0.7465
6
A
168.1286
7.5293
7
A
187.9236
1.9730
8
A
220.6048
3.7812
9
A
242.5358
3.2928
10
A
302.8403
4.8552
11
A
354.6354
31.5106
12
A
454.9758
3.6002
13
A
746.1513
23.3574
14
A
831.4630
0.7631
15
A
875.0774
8.4496
16
A
946.9407
3.8599
17
A
980.3637
6.4046
18
A
1016.8984
92.4958
19
A
1030.3731
20.5594
20
A
1067.5744
9.9175
21
A
1122.2913
64.9225
22
A
1170.6431
2.1164
23
A
1273.6283
11.7364
24
A
1332.5476
2.6844
25
A
1337.4126
4.9370
26
A
1412.3997
1.1210
27
A
1434.1344
0.6737
28
A
1468.2137
0.6561
29
A
1493.3322
13.5045
30
A
1514.5000
0.9656
31
A
1519.6835
7.5543
32
A
1532.1905
6.9861
33
A
2191.9966
0.5039
34
A
3035.2809
34.2167
35
A
3038.7922
42.7499
36
A
3070.2804
6.5809
37
A
3073.3131
28.5202
38
A
3100.7906
28.2889
39
A
3108.4567
62.4220
40
A
3112.7493
125.9724
41
A
3269.1807
6.2460
42
A
3385.2534
0.4981
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
TO SUSPECT YOUR OWN MORTALITY IS TO KNOW THE BEGINNING OF TERROR. TO LEARN IRREFUTABLY THAT YOU ARE MORTAL IS TO KNOW THE END OF TERROR. -- JESSICA CHILDREN OF DUNE BY FRANK HERBERT