WebMO Job Summary

525021: C11H24OBr(-1) TS non-Zaitsev tert-butoxide 2-bromohelptane, Transition State Optimization & - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT=(TS,NoEigenTest,CalcFC) SCRF=(PCM,Solvent=2-methyl-2-propanol) Geom=Connectivity FREQ
Stoichiometry C11H24BrO(1-)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -3080.64496546 Hartree
ZPE 0.327277 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -3080.299342 Hartree
Enthalpy -3080.298398 Hartree
Free Energy -3080.366357 Hartree
Cv 65.330 cal/mol-K
Entropy 143.032 cal/mol-K
Dipole Moment 6.6247 Debye
Server batch (538073)
CPU time 78942.9 sec

Geometry Sequence Energies

Step Energy  
0 -3080.62956096  
1 -3080.63800452  
2 -3080.64126846  
3 -3080.64317923  
4 -3080.64388018  
5 -3080.64436482  
6 -3080.64452622  
7 -3080.64478849  
8 -3080.64480682  
9 -3080.64473168  
10 -3080.64486410  
11 -3080.64456721  
12 -3080.64492541  
13 -3080.64494853  
14 -3080.64434357  
15 -3080.64482447  
16 -3080.64416344  
17 -3080.64466071  
18 -3080.64490120  
19 -3080.64490693  
20 -3080.64495495  
21 -3080.64449156  
22 -3080.64491949  
23 -3080.64442919  
24 -3080.64484156  
25 -3080.64429213  
26 -3080.64465995  
27 -3080.64446255  
28 -3080.64467639  
29 -3080.64456857  
30 -3080.64489203  
31 -3080.64494732  
32 -3080.64427698  
33 -3080.64477727  
34 -3080.64443096  
35 -3080.64485850  
36 -3080.64489209  
37 -3080.64495572  
38 -3080.64413199  
39 -3080.64481337  
40 -3080.64487183  
41 -3080.64496132  
42 -3080.64484300  
43 -3080.64495537  
44 -3080.64432001  
45 -3080.64488496  
46 -3080.64449404  
47 -3080.64489840  
48 -3080.64452364  
49 -3080.64488198  
50 -3080.64460980  
51 -3080.64487515  
52 -3080.64492418  
53 -3080.64381525  
54 -3080.64467341  
55 -3080.64484337  
56 -3080.64464820  
57 -3080.64484477  
58 -3080.64493570  
59 -3080.64429562  
60 -3080.64481412  
61 -3080.64481674  
62 -3080.64494233  
63 -3080.64422460  
64 -3080.64474376  
65 -3080.64416545  
66 -3080.64485002  
67 -3080.64466509  
68 -3080.64492747  
69 -3080.64485986  
70 -3080.64480516  
71 -3080.64495816  
72 -3080.64490465  
73 -3080.64496496  
74 -3080.64496477  
75 -3080.64496427  
76 -3080.64434659  
77 -3080.64489015  
78 -3080.64488270  
79 -3080.64496343  
80 -3080.64496380  
81 -3080.64496562  
82 -3080.64496542  
83 -3080.64496541  
84 -3080.64496502  
85 -3080.64496495  
86 -3080.64496527  
87 -3080.64495211  
88 -3080.64496525  
89 -3080.64496498  
90 -3080.64496557  
91 -3080.64496546  
92 -3080.64496546  
93 -3080.64496546  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 0.42110 0.01404638405
b 0.25274 0.00843049894
c 0.16719 0.00557685811

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A -785.0946 9865.9212
2 A 28.8003 2.1329
3 A 45.8453 0.7592
4 A 48.4912 0.3667
5 A 53.2484 0.7176
6 A 68.8867 0.9462
7 A 83.8307 2.9174
8 A 95.2904 9.5139
9 A 120.8443 2.3467
10 A 127.8779 0.9069
11 A 141.9083 1.8724
12 A 147.4962 0.8619
13 A 187.2345 2.0981
14 A 228.9006 0.2543
15 A 249.7180 0.0417
16 A 275.5894 3.1130
17 A 276.2413 0.3729
18 A 281.4973 0.4732
19 A 321.3962 6.5951
20 A 336.5871 4.3573
21 A 342.3956 28.9867
22 A 410.4192 44.9349
23 A 427.3256 3.8258
24 A 439.9966 9.5052
25 A 469.4728 130.3836
26 A 477.8719 14.8717
27 A 495.0982 10.5801
28 A 615.1820 287.5179
29 A 706.8458 1278.1275
30 A 737.2626 70.7811
31 A 739.8237 10.7750
32 A 765.0122 6.4031
33 A 842.2326 27.0778
34 A 871.9838 4.6794
35 A 879.1346 1.4186
36 A 893.7163 3.5789
37 A 938.0263 7.2463
38 A 944.4184 0.0401
39 A 953.3848 7.9449
40 A 964.3997 11.2370
41 A 1004.3406 56.3071
42 A 1019.1743 3.4154
43 A 1041.4838 2.1068
44 A 1043.4283 9.9074
45 A 1045.0982 23.4178
46 A 1064.5655 2.8681
47 A 1072.9103 4.2564
48 A 1099.7235 14.8425
49 A 1143.5522 37.5534
50 A 1196.7891 1.6534
51 A 1220.0454 76.3588
52 A 1235.5093 44.7709
53 A 1237.4816 47.3426
54 A 1246.8012 12.2691
55 A 1277.1190 1.5458
56 A 1285.1706 78.7367
57 A 1310.6591 25.6681
58 A 1336.5682 26.9166
59 A 1341.1358 23.6093
60 A 1343.6549 19.8931
61 A 1386.2393 19.4025
62 A 1396.2187 4.9519
63 A 1398.1952 12.1975
64 A 1413.5454 12.8228
65 A 1419.5984 6.8993
66 A 1423.0918 6.2431
67 A 1433.6488 1.2335
68 A 1448.8253 17.9732
69 A 1493.8324 2.9981
70 A 1497.8299 0.0599
71 A 1502.9012 0.5158
72 A 1504.6735 0.2382
73 A 1506.9246 0.1640
74 A 1513.7754 3.9286
75 A 1514.4260 2.9997
76 A 1517.0268 10.5463
77 A 1517.5329 2.4707
78 A 1520.5937 6.0636
79 A 1527.8151 0.7383
80 A 1531.2943 3.3676
81 A 1537.9397 4.4792
82 A 1577.1895 123.5964
83 A 3006.2211 1.0618
84 A 3010.1228 18.0915
85 A 3011.8563 64.3140
86 A 3013.1267 69.5241
87 A 3017.2930 11.6161
88 A 3023.5183 106.8234
89 A 3024.1323 89.1156
90 A 3035.0742 13.5470
91 A 3037.2081 48.7050
92 A 3056.8659 62.5118
93 A 3064.4560 7.9247
94 A 3069.4368 48.3930
95 A 3075.8627 15.1595
96 A 3076.2954 15.8581
97 A 3085.4802 268.5888
98 A 3085.9585 60.1175
99 A 3091.3971 3.9813
100 A 3094.8233 125.8851
101 A 3096.8524 116.7766
102 A 3100.2497 106.3665
103 A 3104.3131 67.4228
104 A 3129.4841 38.7157
105 A 3166.1636 36.5237
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

... I FELL INTO A REVERIE ... THE ATOMS WERE GAMBOLING BEFORE MY EYES ... I SAW HOW TWO SMALL ONES UNITED TO FORM A PAIR; HOW THE LARGER ONES SEIZED TWO OF THE SMALLER ONES; HOW STILL LARGER ONES KEPT HOLD OF THREE OR FOUR SMALLER ONES ... I SAW HOW THE LARGER ONES FORMED A CHAIN ... THIS WAS THE ORIGIN OF THE STRUCTURE THEORY. -- C.F.KEKULE VON STRADONITZ