WebMO Job Summary

536064: C6H14OCl(-1) E2 trans Zaitsev TS, Transition State Optimization & - Gaussian

Calculated Quantities

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Overview

ÿ ??/TR>
Quantity Value
Route #N B3LYP/6-31G(d) OPT=(TS,NoEigenTest,CalcAll) SCRF=(PCM,Solvent=ethanol) Geom=Connectivity FREQ
Stoichiometry C6H14ClO(1-)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -772.564597545 Hartree
ZPE 0.186328 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -772.366544 Hartree
Enthalpy -772.365600 Hartree
Free Energy -772.417328 Hartree
Cv 39.126 cal/mol-K
Entropy 108.871 cal/mol-K
Dipole Moment 1.5117 Debye
Server batch (549117)
CPU time 27496.6 sec

Geometry Sequence Energies

Step Energy  
0 -772.366129157  
1 -772.506080247  
2 -772.553429416  
3 -772.563173798  
4 -772.563775381  
5 -772.563325757  
6 -772.563836044  
7 -772.564356215  
8 -772.564554349  
9 -772.564563876  
10 -772.564566023  
11 -772.564570677  
12 -772.564581652  
13 -772.564590342  
14 -772.564597239  
15 -772.564597545  
16 -772.564597545  
17 -772.564597545  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.98591 0.09959923675
b 0.57550 0.01919661368
c 0.50663 0.01689935776

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A -582.2567 5999.5604
2 A 37.5144 0.6350
3 A 59.1105 4.9408
4 A 68.3036 25.9374
5 A 81.6828 10.5397
6 A 131.8591 5.2619
7 A 157.6541 11.3374
8 A 178.6174 2.2265
9 A 201.7571 4.5898
10 A 253.5710 1.0875
11 A 274.8896 7.4953
12 A 288.7576 1.5648
13 A 316.9419 15.8192
14 A 430.6481 45.3058
15 A 470.1569 11.6637
16 A 489.1620 11.9949
17 A 803.2365 1.2529
18 A 821.2378 1352.4956
19 A 875.8467 38.8186
20 A 879.0704 24.0945
21 A 913.2111 1234.2343
22 A 968.7957 248.0124
23 A 1013.5609 143.8200
24 A 1058.8821 37.0589
25 A 1066.8895 6.7424
26 A 1087.0212 123.3460
27 A 1125.2494 134.8370
28 A 1168.3857 36.0844
29 A 1190.5800 3.2318
30 A 1211.9810 147.0894
31 A 1279.4872 260.3371
32 A 1314.4320 18.3038
33 A 1329.7970 23.7097
34 A 1384.5521 162.2262
35 A 1405.0587 14.1617
36 A 1420.5583 7.8223
37 A 1429.4344 24.3799
38 A 1471.0032 136.8598
39 A 1491.2120 22.4888
40 A 1503.4025 2.6449
41 A 1508.2466 8.1347
42 A 1509.5433 1.6694
43 A 1513.6132 10.5270
44 A 1517.2637 62.9883
45 A 1527.1827 21.6179
46 A 1549.0419 65.2430
47 A 1576.1056 114.4944
48 A 2767.5110 262.5539
49 A 2790.3198 370.2262
50 A 3009.9922 76.2269
51 A 3026.8853 62.0881
52 A 3032.2436 14.2959
53 A 3049.9115 25.7696
54 A 3072.1348 115.2437
55 A 3083.5291 10.6479
56 A 3083.7990 149.5066
57 A 3095.2245 67.3232
58 A 3110.4553 16.1613
59 A 3146.5153 13.5066
60 A 3165.6135 50.3206
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

CLIMB THE MOUNTAINS AND GET THEIR GOOD TIDINGS. NATURE'S PEACE WILL FLOW INTO YOU AS SUNSHINE FLOWS INTO TREES. THE WINDS WILL BLOW THEIR OWN FRESHNESS INTO YOU, AND CARES WILL DROP OFF LIKE AUTUMN LEAVES. -- JOHN MUIR