WebMO Job Summary
551917: C6H5O2NCl(+1) para arenium nitration of chlorobenzene Cs, Optimize + Vib Freq - Gaussian
Raw Output
Save Notes
Calculated Quantities
Expand all
Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
5
ClNO
2
(1+)
Symmetry
CS
Basis
6-31G(d)
RB3LYP Energy
-896.618853162 Hartree
ZPE
0.104031 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-896.506261 Hartree
Enthalpy
-896.505317 Hartree
Free Energy
-896.550056 Hartree
C
v
31.155 cal/mol-K
Entropy
94.160 cal/mol-K
Dipole Moment
3.9568 Debye
Server
batch (564966)
CPU time
1906.3 sec
Geometry Sequence Energies
Step
Energy
0
-896.557484006
1
-896.603160661
2
-896.615681380
3
-896.601761401
4
-896.618181304
5
-896.618616533
6
-896.618796765
7
-896.618821982
8
-896.618838681
9
-896.618847464
10
-896.618852451
11
-896.618853162
12
-896.618853162
13
-896.618853162
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
3.34935
0.11172229023
b
0.58648
0.01956286706
c
0.51738
0.01725793916
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A"
38.8827
0.0421
2
A'
58.3887
5.6484
3
A"
189.5860
6.5808
4
A'
196.3682
0.6049
5
A'
290.5004
19.9960
6
A"
320.0456
0.2013
7
A"
356.5747
0.3177
8
A'
462.3929
0.3375
9
A"
480.6133
0.3970
10
A'
520.0124
6.2553
11
A"
596.4492
5.0903
12
A'
624.9260
39.1610
13
A'
718.9263
3.1290
14
A'
772.4737
14.1762
15
A"
790.3533
0.6541
16
A'
821.2453
273.2485
17
A'
879.2212
51.6467
18
A'
902.2044
110.0270
19
A'
993.7776
6.3481
20
A"
998.3080
0.7821
21
A'
1031.7547
10.7423
22
A"
1087.9727
8.9164
23
A'
1124.0454
270.8122
24
A'
1138.1399
60.7108
25
A"
1155.7772
2.5687
26
A'
1228.7372
1.2231
27
A"
1318.7726
17.5651
28
A"
1376.2778
1.2420
29
A'
1379.8810
242.2374
30
A'
1469.8401
126.3294
31
A"
1470.6225
52.2979
32
A"
1550.7612
63.5180
33
A'
1657.3876
252.9406
34
A"
1741.3245
239.7565
35
A'
2963.3513
51.5686
36
A"
3234.2647
1.4478
37
A'
3234.4932
18.2134
38
A"
3244.0812
34.2808
39
A'
3245.6209
0.9023
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
NOTHING RESEMBLES A NEW PHENOMENON AS MUCH AS A MISTAKE. -- ENRICO FERMI (?)