WebMO Job Summary

556270: H2O3N(+1) OH-protonated nitric acid Cs, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry H2NO3(1+)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -281.158747252 Hartree
ZPE 0.035304 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -281.117837 Hartree
Enthalpy -281.116893 Hartree
Free Energy -281.151687 Hartree
Cv 16.601 cal/mol-K
Entropy 73.229 cal/mol-K
Dipole Moment 1.2359 Debye
Server batch (569333)
CPU time 303.2 sec

Geometry Sequence Energies

Step Energy  
0 -281.153976927  
1 -281.158490438  
2 -281.158666656  
3 -281.158664282  
4 -281.158727000  
5 -281.158734265  
6 -281.158738653  
7 -281.158740200  
8 -281.158745284  
9 -281.158746992  
10 -281.158747252  
11 -281.158747252  
12 -281.158747252  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 12.07601 0.40281233493
b 6.92771 0.23108353179
c 4.41219 0.14717481652

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 94.0903 24.3825
2 A' 171.5906 175.5882
3 A" 254.6738 8.4585
4 A' 311.5490 144.0212
5 A" 538.1869 27.9484
6 A' 567.5733 254.6674
7 A' 619.7990 8.6630
8 A' 1408.2573 49.4187
9 A' 1685.2056 73.7428
10 A" 2361.0929 330.6225
11 A' 3689.5903 163.4369
12 A" 3795.0295 149.2139
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THE RARE EARTHS PERPLEX US IN OUR RESEARCHES, BAFFLE US IN OUR SPECULATIONS, AND HAUNT US IN OUR VERY DREAMS. THEY STRETCH LIKE AN UNKNOWN BEFORE US, MOCKING, MYSTIFYING, AND MURMURING STRANGE REVELATIONS AND POSSIBILITIES. -- SIR WILLIAM CROOKE, 1832-1919