WebMO Job Summary

556342: C8H17OCl 2-chloro,2-5-hexan-2-ol, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry C8H17ClO
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -850.531082411 Hartree
ZPE 0.240762 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -850.277281 Hartree
Enthalpy -850.276336 Hartree
Free Energy -850.329476 Hartree
Cv 48.791 cal/mol-K
Entropy 111.842 cal/mol-K
Dipole Moment 3.1016 Debye
Server batch (569405)
CPU time 6293.8 sec

Geometry Sequence Energies

Step Energy  
0 -850.509954095  
1 -850.527176285  
2 -850.530054626  
3 -850.530866836  
4 -850.531052589  
5 -850.531073448  
6 -850.531081189  
7 -850.531082360  
8 -850.531082411  
9 -850.531082411  
10 -850.531082411  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 1.82340 0.06082207712
b 0.54390 0.01814255114
c 0.51582 0.01720590316

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 22.9996 2.5524
2 A 67.9292 4.0151
3 A 122.4290 1.8352
4 A 137.0540 0.7646
5 A 196.5314 1.0837
6 A 234.8136 2.1649
7 A 256.1732 0.0542
8 A 261.2063 0.2034
9 A 275.5188 3.2083
10 A 285.0800 23.0100
11 A 290.3607 117.2775
12 A 311.0043 1.5925
13 A 328.9424 18.4066
14 A 341.9281 9.0037
15 A 359.9417 19.4368
16 A 404.6999 3.6958
17 A 430.7929 10.1684
18 A 453.2871 11.9095
19 A 493.0671 27.2973
20 A 517.6508 54.8683
21 A 550.2713 15.0516
22 A 762.1342 2.3918
23 A 779.3729 2.0209
24 A 835.8483 39.6613
25 A 919.8449 1.2798
26 A 928.4754 31.0416
27 A 940.9857 12.7990
28 A 954.1687 1.3297
29 A 966.6005 18.7670
30 A 1001.7524 0.9955
31 A 1030.7364 0.1629
32 A 1055.1817 9.6263
33 A 1082.4524 8.8575
34 A 1117.6056 152.8811
35 A 1168.4326 45.9456
36 A 1171.7288 25.6549
37 A 1198.0971 11.2887
38 A 1230.2969 12.9263
39 A 1258.4554 33.6493
40 A 1287.8060 38.0900
41 A 1343.9142 12.5924
42 A 1357.7370 5.8177
43 A 1391.5248 72.4086
44 A 1423.5618 7.6031
45 A 1426.2305 5.8985
46 A 1428.3686 13.2262
47 A 1440.9620 9.2928
48 A 1445.3452 4.7874
49 A 1492.7310 0.0928
50 A 1501.1403 1.9354
51 A 1504.8672 0.2002
52 A 1508.4875 3.0684
53 A 1511.3406 0.2757
54 A 1514.2004 3.5858
55 A 1515.3100 8.5976
56 A 1523.2054 0.8094
57 A 1529.1925 3.7793
58 A 1531.9593 18.2600
59 A 3041.3209 24.4908
60 A 3046.6067 25.6175
61 A 3052.0402 10.1415
62 A 3053.5805 15.1962
63 A 3060.5239 30.7822
64 A 3060.8982 48.0155
65 A 3090.8577 3.5446
66 A 3104.8979 4.3830
67 A 3108.5199 55.6855
68 A 3111.5031 79.7259
69 A 3122.6294 21.0015
70 A 3123.2608 67.2329
71 A 3127.4974 44.2597
72 A 3133.0263 44.5618
73 A 3144.0630 35.8643
74 A 3153.7523 30.9344
75 A 3725.6287 18.5209
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IT WAS AN ACT OF DESPARATION. FOR SIX YEARS I HAD STRUGGLED WITH THE BLACKBODY THEORY. I KNEW THE PROBLEM WAS FUNDAMENTAL, AND I KNEW THE ANSWER. I HAD TO FIND A THEORETICAL EXPLANATION AT ANY COST, EXCEPT FOR THE INVIOLABLITY OF THE TWO LAWS OF THERMODYNAMICS. -- MAX PLANCK, 1931