WebMO Job Summary

556374: H3O(+1) hydronium in water, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry H3O(1+)
Symmetry C3V
Basis 6-31G(d)
RB3LYP Energy -76.689084819 Hartree
ZPE 0.034307 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -76.651888 Hartree
Enthalpy -76.650944 Hartree
Free Energy -76.672898 Hartree
Cv 6.530 cal/mol-K
Entropy 46.206 cal/mol-K
Dipole Moment 1.6770 Debye
Server batch (569437)
CPU time 98.7 sec

Geometry Sequence Energies

Step Energy  
0 -76.6810853138  
1 -76.6887197944  
2 -76.6890510321  
3 -76.6890843324  
4 -76.6890848190  
5 -76.6890848190  
6 -76.6890848190  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 323.72710 10.79837372026
b 323.72710 10.79837372026
c 186.88487 6.23380825678

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A1 902.0128 530.6129
2 E 1710.2102 117.6502
3 E 1710.2102 117.6500
4 A1 3515.1325 52.3474
5 E 3610.6529 493.6553
6 E 3610.6529 493.6547
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

"ANNA, YOU MUSN'T SPEAK OF OXIDIZED MURIATIC ACID ANYMORE, FROM NOW ON YOU MUST SAY CHLORINE." -- JENS JACOB BERZELIUS, IN 1820, TO HIS COOK, WHO HAD COMPLAINED OF THE SMELL OF THE FLASK SHE WAS CLEANING.