WebMO Job Summary

556521: C8H8O2 4-formylanisole in ethanol, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Methanol) Geom=Connectivity
Stoichiometry C8H8O2
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -460.106514777 Hartree
ZPE 0.143030 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -459.954644 Hartree
Enthalpy -459.953700 Hartree
Free Energy -459.997472 Hartree
Cv 33.007 cal/mol-K
Entropy 92.126 cal/mol-K
Dipole Moment 5.1346 Debye
Server batch (569584)
CPU time 2191.9 sec

Geometry Sequence Energies

Step Energy  
0 -460.077160241  
1 -460.102885932  
2 -460.106161125  
3 -460.106497881  
4 -460.106513028  
5 -460.106514777  
6 -460.106514777  
7 -460.106514777  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.15222 0.13850315074
b 0.71337 0.02379546186
c 0.61116 0.02038610324

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 80.6203 0.0287
2 A" 117.9207 17.0877
3 A' 173.4426 12.8455
4 A" 198.6869 2.0372
5 A" 238.5177 0.5760
6 A' 280.6707 2.1590
7 A" 337.2754 8.0662
8 A' 371.4882 0.3927
9 A" 431.4825 0.6879
10 A' 516.2518 13.8577
11 A" 525.5912 8.9076
12 A' 606.0294 75.6227
13 A' 643.3290 2.7093
14 A" 724.6680 0.0201
15 A' 779.8096 13.1261
16 A" 834.3339 0.1772
17 A" 845.7756 84.6664
18 A' 862.3655 52.1607
19 A" 967.8750 0.0013
20 A" 977.8280 0.0015
21 A' 1022.9465 0.8902
22 A" 1038.5536 0.0555
23 A' 1053.6040 94.4696
24 A' 1140.9473 16.1352
25 A" 1179.9849 1.3535
26 A' 1183.6479 292.3441
27 A' 1214.4192 15.1200
28 A' 1250.1495 131.8815
29 A' 1304.4446 524.4509
30 A' 1338.8774 18.7424
31 A' 1366.3568 158.3657
32 A' 1445.6183 7.9470
33 A' 1475.1988 9.6195
34 A' 1496.8595 19.2236
35 A" 1514.3731 9.7808
36 A' 1522.6548 63.7945
37 A' 1559.6985 69.5078
38 A' 1619.1504 20.9674
39 A' 1652.3299 585.4147
40 A' 1760.0129 444.2947
41 A' 2927.6659 225.0391
42 A' 3049.2719 66.4357
43 A" 3117.9086 42.1716
44 A' 3175.2588 26.9655
45 A' 3190.4924 13.6323
46 A' 3211.3835 5.1501
47 A' 3219.5757 10.4515
48 A' 3237.4841 10.4889
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

I KNOW YOU BELIEVE YOU UNDERSTAND WHAT YOU THINK I SAID, BUT I AM NOT SURE YOU REALIZE THAT WHAT YOU HEARD IS NOT WHAT I MEANT.