WebMO Job Summary

556635: C9H11N2(+1) alpha-aminonitrile protonated at amino in water, Optimize + Vib Freq - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry C9H11N2(1+)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -458.90993445 Hartree
ZPE 0.189639 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -458.710301 Hartree
Enthalpy -458.709357 Hartree
Free Energy -458.756286 Hartree
Cv 37.920 cal/mol-K
Entropy 98.770 cal/mol-K
Dipole Moment 15.5496 Debye
Server batch (569698)
CPU time 6332 sec

Geometry Sequence Energies

Step Energy  
0 -458.901202124  
1 -458.907921115  
2 -458.908908035  
3 -458.909549176  
4 -458.909840313  
5 -458.909915882  
6 -458.909931156  
7 -458.909932855  
8 -458.909933210  
9 -458.909934597  
10 -458.909934450  
11 -458.909934450  
12 -458.909934450  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.14139 0.07142908178
b 0.67181 0.02240916948
c 0.57617 0.01921896247

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 50.7306 6.5978
2 A 71.8155 6.4338
3 A 119.3719 18.9869
4 A 169.4123 12.5871
5 A 225.9388 7.6005
6 A 272.9074 4.8635
7 A 287.8437 11.3962
8 A 323.9010 14.1650
9 A 366.1002 0.2526
10 A 418.3544 0.0240
11 A 492.8688 6.7208
12 A 557.7255 11.2141
13 A 574.9883 5.4943
14 A 614.9568 3.7918
15 A 634.3129 0.1080
16 A 715.0704 32.9225
17 A 758.0809 48.9687
18 A 810.0357 0.5974
19 A 832.6570 0.1476
20 A 865.2398 0.0330
21 A 934.6851 19.4334
22 A 940.8053 9.6717
23 A 961.6192 6.5614
24 A 980.5685 0.0442
25 A 1009.7977 0.0705
26 A 1017.0337 3.7455
27 A 1021.2233 23.8458
28 A 1057.9985 5.4998
29 A 1092.9944 5.8896
30 A 1126.0833 28.9816
31 A 1181.7568 57.8216
32 A 1190.8048 0.0218
33 A 1215.3482 0.3045
34 A 1230.9087 0.2844
35 A 1246.4294 1.7332
36 A 1354.6508 1.5766
37 A 1366.6770 5.2997
38 A 1376.0763 2.0549
39 A 1398.4918 0.3516
40 A 1421.3147 29.5471
41 A 1503.7305 12.7958
42 A 1519.5458 10.3313
43 A 1546.8556 10.9429
44 A 1580.7461 206.3609
45 A 1642.9923 0.6396
46 A 1661.2666 0.3725
47 A 1688.3411 73.4700
48 A 1696.2903 76.5219
49 A 2382.4779 1.5024
50 A 3078.4095 16.8508
51 A 3126.6907 6.8279
52 A 3142.3575 0.1409
53 A 3184.5797 9.7654
54 A 3189.2341 4.9786
55 A 3197.6969 12.9423
56 A 3206.9432 46.6989
57 A 3216.7478 22.3099
58 A 3404.6972 100.5822
59 A 3490.2138 159.0010
60 A 3494.5700 163.3511
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

KEEP CLOSE TO NATURES HEART, YOURSELF; AND BREAK CLEAR AWAY, ONCE IN A WHILE, AND CLIMB A MOUNTAIN OR SPEND A WEEK IN THE WOODS. WASH YOUR SPIRIT CLEAN... -- JOHN MUIR