WebMO Job Summary

556639: C4H6ON(-1) cyanohydrin intermediate transition state with freq C, Transition State Optimization & - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT=(TS,NoEigenTest,NewEstmFC) Geom=Connectivity FREQ
Stoichiometry C4H6NO(1-)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -285.993191179 Hartree
ZPE 0.090875 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -285.895371 Hartree
Enthalpy -285.894427 Hartree
Free Energy -285.932898 Hartree
Cv 23.374 cal/mol-K
Entropy 80.969 cal/mol-K
Dipole Moment 4.8926 Debye
Server batch (569702)
CPU time 353.3 sec

Geometry Sequence Energies

Step Energy  
0 -285.993191046  
1 -285.993191179  
2 -285.993191179  
3 -285.993191179  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.89080 0.16313952768
b 2.49356 0.08317620852
c 2.38920 0.07969513362

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A' -187.8616 150.3954
2 A" 107.3282 1.9350
3 A' 130.5381 20.0125
4 A" 243.6825 0.1495
5 A' 259.4931 1.5467
6 A' 331.5119 0.9826
7 A" 362.6467 0.4986
8 A' 412.1561 5.6530
9 A" 509.4839 12.3525
10 A' 523.2505 34.0922
11 A' 777.9431 22.7984
12 A" 864.6700 13.5093
13 A" 986.3942 1.0977
14 A' 1068.2550 7.1117
15 A' 1107.7647 84.9722
16 A" 1199.2325 84.5777
17 A" 1384.3330 14.2263
18 A' 1392.6601 1.9528
19 A' 1497.0175 35.2499
20 A" 1497.3185 0.0342
21 A" 1505.6298 0.5030
22 A' 1517.7946 10.3164
23 A' 1587.8975 214.8611
24 A' 2213.4087 0.7080
25 A" 2998.5995 23.4955
26 A' 3005.5075 109.6307
27 A" 3071.9780 4.3392
28 A' 3081.6426 111.0211
29 A" 3124.1769 33.4437
30 A' 3127.2205 54.5557
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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